Department of Chemistry2024-12-2920231300-052710.55730/1300-0527.35912-s2.0-85176128073https://doi.org/10.55730/1300-0527.3591https://hdl.handle.net/20.500.14288/23552A comprehensive review of the structure-morphology-property relations in segmented thermoplastic polyurethanes and polyureas (TPU) is provided. Special emphasis is given to the influence of the soft segment structure, polarity, and molecular weight, diisocyanate symmetry and the nature, extent, and strength of hydrogen bonding on the morphology and thermal and mechanical properties of TPUs. Experimental results obtained on composition-dependent TPU morphology and properties by various techniques were also compared by the morphology profiles generated by computational methods such as quantum mechanical calculations and molecular dynamics simulations.ChemistryMultidisciplinaryEngineeringChemicalJournal article1099801900010Q341695