Department of Chemical and Biological EngineeringDepartment of Chemistry2024-11-0920192155-543510.1021/acscatal.9b022312-s2.0-85071948055http://dx.doi.org/10.1021/acscatal.9b02231https://hdl.handle.net/20.500.14288/12847Atomically dispersed iridium complexes were anchored on a reduced graphene aerogel (rGA) by the reaction of Ir(CO)(2)(acac) [acac = acetonylacetonato] with oxygen-containing groups on the rGA. Characterization by X-ray absorption, infrared, and X-ray photoelectron spectroscopies and atomic resolution aberration-corrected scanning transmission electron microscopy demonstrates atomically dispersed iridium, at the remarkably high loading of 14.8 wt %. The rGA support offers sites for metal bonding comparable to those of metal oxides, but with the advantages of high density and a relatively high degree of uniformity, as indicated by the same turnover frequencies for catalytic hydrogenation of ethylene at low and high iridium loadings. The atomic dispersion at a high metal loading- and the high density of catalytic sites per unit of reactor volume, a key criterion for practical catalysts-set this catalyst apart from those reported.ChemistryPhysicalJournal Article494549700022Q1617