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Homogenous photopolymerization of acrylic monomers initiated with ZnO-methacrylate in non-aqueous medium and production of luminescent nanocomposites

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Morlet-Savary, Fabrice
Lalevee, Jacques

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Abstract

Luminescent ZnO/methacrylic acid was demonstrated as an active photoinitiator in the free radical polymerization of vinyl monomers in bulk and in organic solvent without a protic solvent or a co-catalyst, producing luminescent nanocomposites for the first time. Excitation between 320 and 390 nm provided the best results but PEGDA was also successfully initiated at 400-500 nm.

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Royal Society Chemistry

Subject

Polymers, Polymerization

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Polymer Chemistry

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10.1039/c7py02030a

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