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Synthesis and crystal structures of the polygermanide ammoniates K(4)Ge(9)(center dot)9NH(3), Rb(4)Ge(9)(center dot)5NH(3) and Cs(6)Ge(18)(center dot)4NH(3)

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dc.contributor.coauthorSuchentrunk, Christof
dc.contributor.coauthorDaniels, Jörg
dc.contributor.coauthorCarrillo-Cabrera, Wilder
dc.contributor.coauthorKorber, Nikolaus
dc.contributor.departmentDepartment of Chemistry
dc.contributor.kuauthorSomer, Mehmet Suat
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-09T23:13:18Z
dc.date.issued2005
dc.description.abstractThe new compounds K4Ge9 center dot 9 NH3 and Rb4Ge9 center dot 5 NH3 were prepared by the extraction of K4Ge9 and Rb4Ge9 with liquid ammonia and characterized by low temperature X-ray structure analysis. They both contain monocapped square antiprismatic Ge-9(4-) anions. Cs6Ge18 center dot 4 NH3 was prepared by the extraction of K2Cs2Ge9 with liquid ammonia in the presence of [(Bu)(3)MeN](Br2I) as an oxidizing agent, and contains a [Ge-9-Ge-9](6-) dimer in which two Ge-9(4-) anions are linked by a single Ge-Ge bond.
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.issue3
dc.description.openaccessYES
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuN/A
dc.description.volume60
dc.identifier.doi10.1515/znb-2005-0307
dc.identifier.eissn1865-7117
dc.identifier.issn0932-0776
dc.identifier.quartileQ4
dc.identifier.scopus2-s2.0-17744381157
dc.identifier.urihttps://doi.org/10.1515/znb-2005-0307
dc.identifier.urihttps://hdl.handle.net/20.500.14288/9962
dc.identifier.wos228913100007
dc.keywordsZintl anion
dc.keywordsGermanide
dc.keywordsLow-temperature crystal structure analysis
dc.keywordsLiquid ammonia
dc.keywordsSolvate crystal zintl ion
dc.language.isoeng
dc.publisherWalter De Gruyter Gmbh
dc.relation.ispartofZeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences
dc.subjectChemistry
dc.subjectChemistry, inorganic
dc.subjectNuclear chemistry
dc.titleSynthesis and crystal structures of the polygermanide ammoniates K(4)Ge(9)(center dot)9NH(3), Rb(4)Ge(9)(center dot)5NH(3) and Cs(6)Ge(18)(center dot)4NH(3)
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorSomer, Mehmet Suat
local.publication.orgunit1College of Sciences
local.publication.orgunit2Department of Chemistry
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relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb
relation.isParentOrgUnitOfPublicationaf0395b0-7219-4165-a909-7016fa30932d
relation.isParentOrgUnitOfPublication.latestForDiscoveryaf0395b0-7219-4165-a909-7016fa30932d

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