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Synthesis and crystal structures of the polygermanide ammoniates K(4)Ge(9)(center dot)9NH(3), Rb(4)Ge(9)(center dot)5NH(3) and Cs(6)Ge(18)(center dot)4NH(3)

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dc.contributor.coauthorSuchentrunk, Christof
dc.contributor.coauthorDaniels, Jörg
dc.contributor.coauthorCarrillo-Cabrera, Wilder
dc.contributor.coauthorKorber, Nikolaus
dc.contributor.departmentDepartment of Chemistry
dc.contributor.departmentDepartment of Chemistry
dc.contributor.kuauthorSomer, Mehmet Suat
dc.contributor.kuprofileFaculty Member
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.contributor.yokid178882
dc.date.accessioned2024-11-09T23:13:18Z
dc.date.issued2005
dc.description.abstractThe new compounds K4Ge9 center dot 9 NH3 and Rb4Ge9 center dot 5 NH3 were prepared by the extraction of K4Ge9 and Rb4Ge9 with liquid ammonia and characterized by low temperature X-ray structure analysis. They both contain monocapped square antiprismatic Ge-9(4-) anions. Cs6Ge18 center dot 4 NH3 was prepared by the extraction of K2Cs2Ge9 with liquid ammonia in the presence of [(Bu)(3)MeN](Br2I) as an oxidizing agent, and contains a [Ge-9-Ge-9](6-) dimer in which two Ge-9(4-) anions are linked by a single Ge-Ge bond.
dc.description.indexedbyWoS
dc.description.indexedbyScopus
dc.description.issue3
dc.description.openaccessYES
dc.description.publisherscopeInternational
dc.description.volume60
dc.identifier.doi10.1515/znb-2005-0307
dc.identifier.eissn1865-7117
dc.identifier.issn0932-0776
dc.identifier.quartileQ4
dc.identifier.scopus2-s2.0-17744381157
dc.identifier.urihttp://dx.doi.org/10.1515/znb-2005-0307
dc.identifier.urihttps://hdl.handle.net/20.500.14288/9962
dc.identifier.wos228913100007
dc.keywordsZintl anion
dc.keywordsGermanide
dc.keywordsLow-temperature crystal structure analysis
dc.keywordsLiquid ammonia
dc.keywordsSolvate crystal zintl ion
dc.languageEnglish
dc.publisherWalter De Gruyter Gmbh
dc.sourceZeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences
dc.subjectChemistry
dc.subjectChemistry, inorganic
dc.subjectNuclear chemistry
dc.titleSynthesis and crystal structures of the polygermanide ammoniates K(4)Ge(9)(center dot)9NH(3), Rb(4)Ge(9)(center dot)5NH(3) and Cs(6)Ge(18)(center dot)4NH(3)
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.authorid0000-0001-5606-9101
local.contributor.kuauthorSomer, Mehmet Suat
relation.isOrgUnitOfPublication035d8150-86c9-4107-af16-a6f0a4d538eb
relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb

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