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Synthesis and crystal structures of the polygermanide ammoniates K4Ge9·9 NH3, Rb4Ge9·5 NH3 and Cs6Ge18·4 NH3

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dc.contributor.coauthorSuchentrunk, Christof
dc.contributor.coauthorDaniels, Jörg
dc.contributor.coauthorCarrillo-Cabrera, Wilder
dc.contributor.coauthorKorber, Nikolaus
dc.contributor.departmentDepartment of Chemistry
dc.contributor.facultymemberYes
dc.contributor.kuauthorSomer, Mehmet Suat
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-09T23:13:18Z
dc.date.issued2005
dc.description.abstractThe new compounds K4Ge9·9 NH3 and Rb4Ge9·5 NH3 were prepared by the extraction of K4Ge9 and Rb4Ge9 with liquid ammonia and characterized by low temperature X-ray structure analysis. They both contain monocapped square antiprismatic Ge94- anions. Cs6Ge18·4 NH3 was prepared by the extraction of K2Cs2Ge9 with liquid ammonia in the presence of [(Bu)3MeN](Br2I) as an oxidizing agent, and contains a [Ge9-Ge9]6- dimer in which two Ge94- anions are linked by a single Ge-Ge bond.
dc.description.fulltextNo
dc.description.harvestedfromManual
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.openaccessYES
dc.description.peerreviewstatusN/A
dc.description.publisherscopeInternational
dc.description.readpublishN/A
dc.description.sponsoredbyTubitakEuN/A
dc.description.studentonlypublicationNo
dc.description.studentpublicationNo
dc.description.versionN/A
dc.identifier.WoSQuartileQ3
dc.identifier.doi10.1515/znb-2005-0307
dc.identifier.eissn1865-7117
dc.identifier.embargoN/A
dc.identifier.endpage283
dc.identifier.issn0932-0776
dc.identifier.issue3
dc.identifier.scopus2-s2.0-17744381157
dc.identifier.startpage277
dc.identifier.urihttps://doi.org/10.1515/znb-2005-0307
dc.identifier.urihttps://hdl.handle.net/20.500.14288/9962
dc.identifier.volume60
dc.identifier.wos000228913100007
dc.keywordsZintl anion
dc.keywordsGermanide
dc.keywordsLow-temperature crystal structure analysis
dc.keywordsLiquid ammonia
dc.keywordsSolvate crystal
dc.language.isoeng
dc.publisherDe Gruyter
dc.relation.affiliationKoç University
dc.relation.collectionKoç University Institutional Repository
dc.relation.ispartofZeitschrift fur Naturforschung Section B - A Journal of Chemical Sciences
dc.relation.openaccessN/A
dc.rightsN/A
dc.subjectInorganic chemistry
dc.subjectSolid state chemistry
dc.subjectCrystal structure
dc.subjectZintl phases
dc.titleSynthesis and crystal structures of the polygermanide ammoniates K4Ge9·9 NH3, Rb4Ge9·5 NH3 and Cs6Ge18·4 NH3
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorSomer, Mehmet Suat
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relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb
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