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Thermodynamics and dynamics of adsorption of metal complexes on surfaces from supercritical solutions

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dc.contributor.coauthorN/A
dc.contributor.departmentDepartment of Chemical and Biological Engineering
dc.contributor.facultymemberYes
dc.contributor.kuauthorErkey, Can
dc.contributor.schoolcollegeinstituteCollege of Engineering
dc.date.accessioned2024-11-09T23:14:55Z
dc.date.issued2011
dc.description.abstractThe chapter is on the adsorption phenomena of metal complexes on substrates in the presence of SCFs important in a wide variety of applications ranging from synthesis of nanostructured materials to extraction of metals from surfaces. After describing the thermodynamics of adsorption for fluids and supercritical mixtures, the studies in the literature on adsorption in the presence of SCFs are summarized and discussed. The techniques to measure the adsorption isotherms of metal complexes on porous substrates in the presence of SCFs are described. Primarily, batch adsorption, frontal analysis chromatography and pulse chromatography techniques are covered in detail. The data in the literature on adsorption isotherms of metal complexes are discussed. The equations for modeling the kinetics of batch adsorption of metal complexes are provided together with the solutions of these equations for prediction of data in the literature on kinetics of adsorption of a ruthenium complex on a porous carbon in the presence of scCO2.
dc.description.fulltextNo
dc.description.harvestedfromManual
dc.description.indexedbyScopus
dc.description.indexedbyWOS
dc.description.openaccessYES
dc.description.peerreviewstatusN/A
dc.description.publisherscopeInternational
dc.description.readpublishN/A
dc.description.sponsoredbyTubitakEuN/A
dc.description.studentonlypublicationNo
dc.description.studentpublicationNo
dc.description.versionN/A
dc.identifier.WoSQuartileN/A
dc.identifier.doi10.1016/B978-0-08-045329-3.00004-4
dc.identifier.embargoN/A
dc.identifier.endpage77
dc.identifier.isbn9780080453293
dc.identifier.isbn9780080914480
dc.identifier.issn2212-0505
dc.identifier.scopus2-s2.0-84872403761
dc.identifier.startpage41
dc.identifier.urihttps://doi.org/10.1016/B978-0-08-045329-3.00004-4
dc.identifier.urihttps://hdl.handle.net/20.500.14288/10241
dc.identifier.volume1
dc.identifier.wos000311042000006
dc.keywordsAdsorption
dc.keywordsMetal complexes
dc.keywordsSupercritical carbon dioxide
dc.keywordsAdsorption isotherms
dc.keywordsAdsorption kinetics
dc.keywordsPorous substrates
dc.keywordsSupercritical deposition
dc.keywordsThermodynamics
dc.language.isoeng
dc.publisherElsevier
dc.relation.affiliationKoç University
dc.relation.collectionKoç University Institutional Repository
dc.relation.ispartofSupercritical Fluids and Organometallic Compounds: From Recovery of Trace Metals to Synthesis of Nanostructured Materials
dc.relation.openaccessN/A
dc.rightsN/A
dc.subjectAdsorption of metal complexes from supercritical fluids
dc.subjectSupercritical fluid adsorption
dc.subjectAdsorption thermodynamics in scCO2
dc.titleThermodynamics and dynamics of adsorption of metal complexes on surfaces from supercritical solutions
dc.typeBook Chapter
dspace.entity.typePublication
local.contributor.kuauthorErkey, Can
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