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Micro-phase separation via spinodal-like decomposition in hexamethylynediisocyanate (HDI)-polyurea

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dc.contributor.coauthorKulkarni, Amit S.
dc.contributor.coauthorBeaucage, Gregory
dc.contributor.coauthorWilkes, Garth L.
dc.contributor.coauthorDas, Sudipto
dc.contributor.departmentDepartment of Chemistry
dc.contributor.facultymemberYes
dc.contributor.kuauthorYılgör, İskender
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-09T23:37:15Z
dc.date.issued2012
dc.description.abstractMicro-phase separation in hexamethylynediisocyanate-polyurea was studied using small-angle X-ray scattering and infrared absorption. It was found that phase separation in this system followed spinodal-like decomposition on a 3-4 nm size scale with phase separation occuring on a time scale of days.
dc.description.fulltextNo
dc.description.harvestedfromManual
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.openaccessNO
dc.description.peerreviewstatusN/A
dc.description.publisherscopeInternational
dc.description.readpublishN/A
dc.description.sponsoredbyTubitakEuN/A
dc.description.sponsorshipUse of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. USAXS data was collected at the X-ray Operations and Research beamline 32-ID-B,C at the Advanced Photon Source, Argonne National Laboratory with the assistance of Dr. Jan Ilavsky.
dc.description.studentonlypublicationNo
dc.description.studentpublicationNo
dc.description.versionN/A
dc.identifier.WoSQuartileQ1
dc.identifier.doi10.1007/s10904-012-9669-9
dc.identifier.eissn1574-1451
dc.identifier.embargoN/A
dc.identifier.endpage628
dc.identifier.issn1574-1443
dc.identifier.issue3
dc.identifier.scopus2-s2.0-84860448525
dc.identifier.startpage624
dc.identifier.urihttps://doi.org/10.1007/s10904-012-9669-9
dc.identifier.urihttps://hdl.handle.net/20.500.14288/12773
dc.identifier.volume22
dc.identifier.wos000303417300009
dc.keywordsMicro-phase separation
dc.keywordsSpinodal decompostion
dc.keywordsPolyurea
dc.keywordsSmall-angle X-Ray scattering nonuniform system
dc.keywordsPhase-separation
dc.keywordsFree-energy
dc.keywordsSynchrotron saxs
dc.keywordsKinetics
dc.keywordsPolyurethane
dc.keywordsBlends
dc.language.isoeng
dc.publisherSpringer
dc.relation.affiliationKoç University
dc.relation.collectionKoç University Institutional Repository
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materials
dc.relation.openaccessN/A
dc.rightsN/A
dc.subjectPolymers
dc.subjectPolymerization
dc.titleMicro-phase separation via spinodal-like decomposition in hexamethylynediisocyanate (HDI)-polyurea
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorYılgör, İskender
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