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Micro-phase separation via spinodal-like decomposition in hexamethylynediisocyanate (HDI)-polyurea

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dc.contributor.coauthorKulkarni, Amit S.
dc.contributor.coauthorBeaucage, Gregory
dc.contributor.coauthorWilkes, Garth L.
dc.contributor.coauthorDas, Sudipto
dc.contributor.departmentDepartment of Chemistry
dc.contributor.kuauthorYılgör, İskender
dc.contributor.kuprofileFaculty Member
dc.contributor.otherDepartment of Chemistry
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.contributor.yokid24181
dc.date.accessioned2024-11-09T23:37:15Z
dc.date.issued2012
dc.description.abstractMicro-phase separation in hexamethylynediisocyanate-polyurea was studied using small-angle X-ray scattering and infrared absorption. It was found that phase separation in this system followed spinodal-like decomposition on a 3-4 nm size scale with phase separation occuring on a time scale of days.
dc.description.indexedbyWoS
dc.description.indexedbyScopus
dc.description.issue3
dc.description.openaccessNO
dc.description.publisherscopeInternational
dc.description.sponsorshipU. S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
dc.description.sponsorshipDirect For Mathematical and Physical Scien
dc.description.sponsorshipDivision of Chemistry [0822838] Funding Source: National Science Foundation Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. USAXS data was collected at the X-ray Operations and Research beamline 32-ID-B,C at the Advanced Photon Source, Argonne National Laboratory with the assistance of Dr. Jan Ilavsky.
dc.description.volume22
dc.identifier.doi10.1007/s10904-012-9669-9
dc.identifier.eissn1574-1451
dc.identifier.issn1574-1443
dc.identifier.quartileQ2
dc.identifier.scopus2-s2.0-84860448525
dc.identifier.urihttp://dx.doi.org/10.1007/s10904-012-9669-9
dc.identifier.urihttps://hdl.handle.net/20.500.14288/12773
dc.identifier.wos303417300009
dc.keywordsMicro-phase separation
dc.keywordsSpinodal decompostion
dc.keywordsPolyurea
dc.keywordsSmall-angle X-Ray scattering nonuniform system
dc.keywordsPhase-separation
dc.keywordsFree-energy
dc.keywordsSynchrotron saxs
dc.keywordsKinetics
dc.keywordsPolyurethane
dc.keywordsBlends
dc.languageEnglish
dc.publisherSpringer
dc.sourceJournal of Inorganic and Organometallic Polymers and Materials
dc.subjectPolymers
dc.subjectPolymerization
dc.titleMicro-phase separation via spinodal-like decomposition in hexamethylynediisocyanate (HDI)-polyurea
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.authorid0000-0002-7756-4192
local.contributor.kuauthorYılgör, İskender
relation.isOrgUnitOfPublication035d8150-86c9-4107-af16-a6f0a4d538eb
relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb

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