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Facile preparation of N-tert-butyl amides under heat-, metal- and acid-free conditions by using tert-butyl nitrite (TBN) as a practical carbon source

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dc.contributor.departmentKUYTAM (Koç University Surface Science and Technology Center)
dc.contributor.departmentDepartment of Chemistry
dc.contributor.kuauthorPalani, Natarajan
dc.contributor.kuauthorMetin, Önder
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.contributor.schoolcollegeinstituteResearch Center
dc.date.accessioned2025-01-19T10:33:09Z
dc.date.issued2023
dc.description.abstracttert-Butyl nitrite (TBN) is a nontoxic substance that has frequently been used as a source of nitrogen, oxygen, or nitric oxide (NO), but not as a carbon source in chemical transformations. Here, for the first time to the best of our knowledge, we introduced TBN as a source of carbon (tert-butyl group) for the synthesis of highly valuable N-tert-butyl amides from nitriles and water under very mild conditions.
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.indexedbyPubMed
dc.description.issue43
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuN/A
dc.description.sponsorshipThis research work was financially supported by the Scientific and Technological Research Council of Turkey (TUBITAK) under the BIDEB Co-Funded Brain Circulation program with a grant no: 121C351. Additionally, we thank Dr Cagdas-Dag (n2Star, Koc University, Tuerkiye) for his assistance with the NMR measurements.
dc.description.volume59
dc.identifier.doi10.1039/d3cc01168b
dc.identifier.eissn1364-548X
dc.identifier.issn1359-7345
dc.identifier.quartileQ2
dc.identifier.scopus2-s2.0-85160458010
dc.identifier.urihttps://doi.org/10.1039/d3cc01168b
dc.identifier.urihttps://hdl.handle.net/20.500.14288/26556
dc.identifier.wos984883300001
dc.language.isoeng
dc.publisherRoyal Soc Chemistry
dc.relation.grantnoScientific and Technological Research Council of Turkey (TUBITAK) under the BIDEB Brain Circulation program [121C351]
dc.relation.ispartofChemical Communications
dc.subjectChemistry
dc.titleFacile preparation of N-tert-butyl amides under heat-, metal- and acid-free conditions by using tert-butyl nitrite (TBN) as a practical carbon source
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorMetin, Önder
local.contributor.kuauthorPalani, Natarajan
local.publication.orgunit1College of Sciences
local.publication.orgunit1Research Center
local.publication.orgunit2Department of Chemistry
local.publication.orgunit2KUYTAM (Koç University Surface Science and Technology Center)
person.familyNamePalani
person.familyNameMetin
person.givenNameNatarajan
person.givenNameÖnder
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relation.isOrgUnitOfPublication035d8150-86c9-4107-af16-a6f0a4d538eb
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