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Synthesis of ru/pdms nano-composites via supercritial deposition

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dc.contributor.coauthorGe, Minglan
dc.contributor.coauthorBozbag, Selmi E.
dc.contributor.coauthorAyala, Christian J.
dc.contributor.coauthorAindow, Mark
dc.contributor.coauthorErkey, Can
dc.contributor.departmentDepartment of Chemical and Biological Engineering
dc.contributor.departmentKUTEM (Koç University Tüpraş Energy Center)
dc.contributor.kuauthorBozbağ, Selmi Erim
dc.contributor.kuauthorErkey, Can
dc.contributor.schoolcollegeinstituteCollege of Engineering
dc.contributor.schoolcollegeinstituteResearch Center
dc.date.accessioned2024-11-09T23:25:18Z
dc.date.issued2016
dc.description.abstractNanomaterials consisting of Ru nanoparticles dispersed in polydimethylsiloxane films were synthesized by supercritical deposition. The films were impregnated with the organometallic precursor bis(2,2,6,6-tetramethyl-3,5-heptanedionato) (1,5-cyclooctadiene) ruthenium (II) under thermodynamic control in the presence of supercritical carbon dioxide (scCO(2)) at 40 degrees C and 10.34 MPa. The precursor molecules were then converted to metallic Ru by thermal treatment in flowing N-2 at ambient pressure, resulting in well-dispersed nanoparticles with diameters of approximate to 2 nm. (C) 2016 Elsevier B.V. All rights reserved.
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.openaccessNO
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuN/A
dc.description.volume180
dc.identifier.doi10.1016/j.matchemphys.2016.05.058
dc.identifier.eissn1879-3312
dc.identifier.issn0254-0584
dc.identifier.quartileQ2
dc.identifier.scopus2-s2.0-84973531821
dc.identifier.urihttps://doi.org/10.1016/j.matchemphys.2016.05.058
dc.identifier.urihttps://hdl.handle.net/20.500.14288/11356
dc.identifier.wos380077600001
dc.keywordsComposite Materials
dc.keywordsNanostructures
dc.keywordsElectron Microscopy
dc.keywordsThermogravimetric Analysis
dc.keywordsPolymers Carbon-Dioxide
dc.keywordsFluids
dc.keywordsFilms
dc.keywordsCO2
dc.keywordsNanoparticles
dc.keywordsImpewgnation
dc.keywordsReduction
dc.keywordsNanocomposites
dc.keywordsHydrogenation
dc.keywordsPrecursor
dc.language.isoeng
dc.publisherElsevier Science Sa
dc.relation.ispartofMaterials Chemistry and Physics
dc.subjectMaterials Science
dc.titleSynthesis of ru/pdms nano-composites via supercritial deposition
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorBozbağ, Selmi Erim
local.contributor.kuauthorErkey, Can
local.publication.orgunit1College of Engineering
local.publication.orgunit1Research Center
local.publication.orgunit2Department of Chemical and Biological Engineering
local.publication.orgunit2KUTEM (Koç University Tüpraş Energy Center)
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