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Structural patterns and dimensionality in magnesium borophosphates: the crystal structures of Mg2(H2O)[BP3O9(OH)4] and Mg(H2O)2[B2P2O8(OH)2]·H2O

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dc.contributor.coauthorEwald, Bastian
dc.contributor.coauthorProts, Yurii
dc.contributor.coauthorKniep, Rüdiger
dc.contributor.departmentDepartment of Chemistry
dc.contributor.facultymemberNo
dc.contributor.kuauthorÖztan, Yiğit
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-09T22:58:18Z
dc.date.issued2005
dc.description.abstractHydrothermal investigations in the system MgO/B2O3/P2O5(/H2O) yielded two new magnesium borophosphates, Mg2(H2O)[BP3O9(OH)4] and Mg(H2O)2[B2P2O8(OH)2]·H2O. The crystal structures were solved by means of single crystal X-ray diffraction. While the acentric crystal structure of Mg2(H2O)[BP3O9(OH)4] (orthorhombic, P212121 (No. 19), a = 709.44(5) pm, b = 859.70(4) pm, c = 1635.1(1) pm, V = 997.3(3) × 106 pm3, Z = 4) contains 1D infinite chains of magnesium coordination octahedra interconnected by a borophosphate tetramer, Mg(H2O)2[B2P2O8(OH)2]·H2O (monoclinic, P21/c (No. 14), a = 776.04(5) pm, b = 1464.26(9) pm, c = 824.10(4) pm, β = 90.25(1)°, V = 936.44(9) × 106 pm3,Z = 4) represents the first layered borophosphate with 63 net topology. The structures are discussed and classified in terms of structural systematics.
dc.description.fulltextNo
dc.description.harvestedfromManual
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.openaccessNO
dc.description.peerreviewstatusN/A
dc.description.publisherscopeInternational
dc.description.readpublishN/A
dc.description.sponsoredbyTubitakEuN/A
dc.description.studentonlypublicationYes
dc.description.studentpublicationYes
dc.description.versionN/A
dc.identifier.doi10.1002/zaac.200500061
dc.identifier.eissn1521-3749
dc.identifier.embargoN/A
dc.identifier.endpage1621
dc.identifier.issn0044-2313
dc.identifier.issue9
dc.identifier.quartileQ3
dc.identifier.scopus2-s2.0-20444440993
dc.identifier.startpage1615
dc.identifier.urihttps://doi.org/10.1002/zaac.200500061
dc.identifier.urihttps://hdl.handle.net/20.500.14288/7686
dc.identifier.volume631
dc.identifier.wos000230081300013
dc.keywordsMagnesium borophosphates
dc.keywordsHydrothermal synthesis
dc.keywordsOligomer
dc.keywordsLayer structure
dc.keywords63 nets
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.affiliationKoç University
dc.relation.collectionKoç University Institutional Repository
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemiede
dc.relation.ispartofJournal of Inorganic and General Chemistryen
dc.relation.openaccessN/A
dc.rightsN/A
dc.subjectInorganic chemistry
dc.subjectSolid state chemistry
dc.titleStructural patterns and dimensionality in magnesium borophosphates: the crystal structures of Mg2(H2O)[BP3O9(OH)4] and Mg(H2O)2[B2P2O8(OH)2]·H2O
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorÖztan, Yiğit
relation.isOrgUnitOfPublication035d8150-86c9-4107-af16-a6f0a4d538eb
relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb
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