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A ruthenium racemisation catalyst for the synthesis of primary amines from secondary amines

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dc.contributor.coauthorPingen, Dennis
dc.contributor.coauthorSchaller, Max Rudolf
dc.contributor.coauthorVogt, Dieter
dc.contributor.departmentN/A
dc.contributor.kuauthorAltıntaş, Çiğdem
dc.contributor.kuprofileResearcher
dc.contributor.schoolcollegeinstituteN/A
dc.contributor.yokidN/A
dc.date.accessioned2024-11-09T23:45:20Z
dc.date.issued2016
dc.description.abstractA Ru-based half sandwich complex used in amine and alcohol racemization reactions was found to be active in the splitting of secondary amines to primary amines using NH3. Conversions up to 80% along with very high selectivities were achieved. However, after about 80% conversion the catalyst lost activity. Similar to Shvo's catalyst, the complex might deactivate under the influence of ammonia. It was revealed that not NH3 but mainly the primary amine is responsible for the deactivation.
dc.description.indexedbyWoS
dc.description.indexedbyScopus
dc.description.issue29
dc.description.openaccessYES
dc.description.publisherscopeInternational
dc.description.sponsorshipNetherlands Ministry of Economic Affairs
dc.description.sponsorshipNetherlands Ministry of Education, Culture, and Sciences within the framework of the CatchBio program We would like to thank Ton Staring for his technical assistance. This research has been in part funded by the Netherlands Ministry of Economic Affairs and the Netherlands Ministry of Education, Culture, and Sciences within the framework of the CatchBio program.
dc.description.volume45
dc.identifier.doi10.1039/c6dt01525e
dc.identifier.eissn1477-9234
dc.identifier.issn1477-9226
dc.identifier.quartileQ1
dc.identifier.scopus2-s2.0-84979007824
dc.identifier.urihttp://dx.doi.org/10.1039/c6dt01525e
dc.identifier.urihttps://hdl.handle.net/20.500.14288/13819
dc.identifier.wos380344900022
dc.keywordsDynamic kinetic resolution
dc.keywordsCyclopentadienylruthenium complexes
dc.keywordsSelective synthesis
dc.keywordsAmmonia-synthesis
dc.keywordsAlcohols
dc.keywordsAmination
dc.keywordsEfficient
dc.keywordsMetal
dc.keywordsCarbonylation
dc.keywordsReactivities
dc.languageEnglish
dc.publisherRoyal Soc Chemistry
dc.sourceDalton Transactions
dc.subjectChemistry
dc.subjectInorganic nuclear
dc.titleA ruthenium racemisation catalyst for the synthesis of primary amines from secondary amines
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.authorid0000-0003-2160-4674
local.contributor.kuauthorAltıntaş, Çiğdem

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