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Colloidal aluminum antimonide quantum dots

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Sahin, Mehmet
Öztürk, Hande
Ow-Yang, Cleva W.

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AlSb is a less studied member of the III-V semiconductor family, and herein, we report the colloidal synthesis of AlSb quantum dots (QDs) for the first time. Different sizes of colloidal AlSb QDs (5 to 9 nm) were produced by the controlled reaction of AlCl3 and Sb[N(Si(Me)(3))(2)](3) in the presence of superhydride. These colloidal AlSb quantum dots showed excitonic transitions in the UV-A region and a tunable band edge emission (quantum yield of up to 18%) in the blue spectral range. Among all III-V quantum dots, these quantum dots show the brightest core emission in the blue spectral region.

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Amer Chemical Soc

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Chemistry, Physical chemistry, Materials science

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Chemistry of Materials

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10.1021/acs.chemmater.9b00905

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