Effect of Co and Ni substitution on the two magnetostructural phase transitions in Fe1.12Te

Abstract

Here we present the results of high-resolution x-ray diffraction experiments along with specific heat, resistivity, and magnetization measurements of chemically well-characterized Fe1.12-xMx Te (M = Co, Ni) samples. The motivation is to investigate how the two coupled magnetostructural phase transitions in the antiferromagnetic parent compound Fe1.12Te of chalcogenide superconductors can be tuned. While the two-step magnetostructural transition (tetragonal-to-orthorhombic followed by orthorhombic-to-monoclinic) persists in Fe1.10Co0.02Te, only one, tetragonal-to-orthorhombic transition was observed in Fe1.10Ni0.02Te. Upon increasing the Co and Ni substitution, the structural phase transitions and the long-range magnetic order are systematically suppressed without any sign of superconductivity. For high substitution levels (x >= 0.05), a spin-glass-like behavior was observed and the low-temperature structure remains tetragonal. From our results, it can be inferred that the electron doping strongly suppresses the magnetostructural phase transitions.