Publication:
Orthorhombic Ba3[BN2]2: A new structure type for an alkaline earth metal nitrido borate

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dc.contributor.coauthorReckeweg, Olaf
dc.contributor.coauthorDiSalvo, Francis J.
dc.contributor.departmentDepartment of Chemistry
dc.contributor.kuauthorSomer, Mehmet Suat
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-09T22:51:59Z
dc.date.issued2003
dc.description.abstractYellow, transparent single crystals of Ba-3[BN2](2) (P2(1)2(1)2(1) (No. 19), a = 424.73(2), b = 1105.60(4) and c = 1475.72(6) pm, Z = 4) are obtained by the reaction of Ba2N and BN in arc-welded Nb ampoules at 1300 K. The title compound crystallizes, despite its familiar 3:2:4 stoichiometry, in a new structure type. The vibrational spectra of orthorhombic Ba-3[BN2](2) have been measured and assigned. The IR spectrum reveals strong band splitting arising from the low site symmetry and the presence of two different sets of crystallographically independent [BN2](3-) groups. The new structure and the vibrational data are compared with those previously reported for the cubic form of Ba-3[BN2](2).
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.issue44958
dc.description.openaccessNO
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuN/A
dc.description.volume361
dc.identifier.doi10.1016/S0925-8388(03)00455-9
dc.identifier.eissn1873-4669
dc.identifier.issn0925-8388
dc.identifier.scopus2-s2.0-0141886365
dc.identifier.urihttps://doi.org/10.1016/S0925-8388(03)00455-9
dc.identifier.urihttps://hdl.handle.net/20.500.14288/6949
dc.identifier.wos186125800020
dc.keywordsBarium
dc.keywordsBoron
dc.keywordsNitride
dc.keywordsDinitridoborate anion
dc.keywordsStructure elucidation
dc.keywordsVibrational spectroscopy
dc.keywordsCrystal-structure
dc.keywordsTetrastrontium TRIS (dinitridoborate)
dc.keywordsVibrational-spectra
dc.keywordsBIS (dinitridoborate)
dc.keywordsMG3BN3
dc.keywordsAnion
dc.language.isoeng
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Alloys and Compounds
dc.subjectChemistry
dc.subjectPhysics
dc.subjectChemistry, physical and theoretical
dc.subjectMaterials Science
dc.subjectMetallurgy
dc.titleOrthorhombic Ba3[BN2]2: A new structure type for an alkaline earth metal nitrido borate
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorSomer, Mehmet Suat
local.publication.orgunit1College of Sciences
local.publication.orgunit2Department of Chemistry
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relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb
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