Publication: Sr3[Co(CN)3] and Ba3[Co(CN)3]: Crystal structure, chemical bonding, and conceptional considerations of highly reduced metalates
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KU-Authors
KU Authors
Co-Authors
Hoehn, Peter
Jach, Franziska
Prots, Yurii
Agrestini, Stefano
Wagner, Frank R.
Ruck, Michael
Tjeng, Liu Hao
Kniep, Ruediger
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Abstract
More than meets the eye: The trigonal-planar complex [Co(CN) 3]6- (see structure, Co red, C gray, N green; alkaline-earth-metal counterions are yellow) has some surprises in store. The CN ligand displays variation in bond length and charge, and Co follows a closed-shell (d10) concept. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Source
Publisher
Wiley
Subject
Chemistry
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Source
Angewandte Chemie-International Edition
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DOI
10.1002/anie.201103717
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