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Permanent URI for this collectionhttps://hdl.handle.net/20.500.14288/6
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Publication Open Access Comparative spectroscopic investigation of Tm3+: tellurite glasses for 2-mu m lasing applications(Multidisciplinary Digital Publishing Institute (MDPI), 2018) Kurt, Adnan; Speghini, Adolfo; Bettinelli, Marco; Department of Electrical and Electronics Engineering; Department of Physics; Çankaya, Hüseyin; Görgülü, Adil Tolga; Sennaroğlu, Alphan; Researcher; Master Student; Faculty Member; Department of Electrical and Electronics Engineering; Department of Physics; Koç University Surface Science and Technology Center (KUYTAM) / Koç Üniversitesi Yüzey Teknolojileri Araştırmaları Merkezi (KUYTAM); College of Engineering; College of Sciences; N/A; N/A; 23851We performed a comparative spectroscopic analysis on three novel Tm3+: tellurite-based glasses with the following compositions Tm2O3: TeO2-ZnO (TeZnTm), Tm2O3: TeO2-Nb2O5 (TeNbTm), and Tm3+: TeO2-K2O-Nb2O5 (TeNbKTm), primarily for 2-mu m laser applications. Tellurite glasses were prepared at different doping concentrations in order to investigate the effect of Tm3+ ion concentration as well as host composition on the stimulated emission cross sections and the luminescence quantum efficiencies. By performing Judd-Ofelt analysis, we determined the average radiative lifetimes of the H-3(4) level to be 2.55 +/- 0.07 ms, 2.76 +/- 0.03 ms and 2.57 +/- 0.20 ms for the TeZnTm, TeNbTm and TeNbKTm samples, respectively. We clearly observed the effect of the cross-relaxation, which becomes significant at higher Tm2O3 concentrations, leading to the quenching of 1460-nm emission and enhancement of 1860-nm emission. Furthermore, with increasing Tm2O3 concentrations, we observed a decrease in the fluorescence lifetimes as a result of the onset of non-radiative decay. For the H-3(4) level, the highest obtained quantum efficiency was 32% for the samples with the lowest Tm2O3 ion concentration. For the 1860-nm emission band, the average emission cross section was determined to measure around 6.33 +/- 0.34 x 10(-21) cm(2), revealing the potential of thulium-doped tellurite gain media for 2-mu m laser applications in bulk and fiber configurations.Publication Open Access Plasmon-coupled photocapacitor neuromodulators(American Chemical Society (ACS), 2020) Ülgüt, Burak; Çetin, Arif E.; N/A; N/A; Department of Molecular Biology and Genetics; Department of Electrical and Electronics Engineering; Department of Chemical and Biological Engineering; Melikov, Rustamzhon; Srivastava, Shashi Bhushan; Karatüm, Onuralp; Doğru-Yüksel, Itır Bakış; Jalali, Houman Bahmani; Sadeghi, Sadra; Dikbaş, Uğur Meriç; Kavaklı, İbrahim Halil; Nizamoğlu, Sedat; PhD Student; Researcher; PhD Student; PhD Student; Master Student; Faculty Member; Faculty Member; Department of Molecular Biology and Genetics; Department of Electrical and Electronics Engineering; Department of Chemical and Biological Engineering; Graduate School of Sciences and Engineering; College of Sciences; College of Engineering; N/A; N/A; N/A; N/A; N/A; N/A; N/A; 40319; 130295Efficient transduction of optical energy to bioelectrical stimuli is an important goal for effective communication with biological systems. For that, plasmonics has a significant potential via boosting the light-matter interactions. However, plasmonics has been primarily used for heat-induced cell stimulation due to membrane capacitance change (i.e., optocapacitance). Instead, here, we demonstrate that plasmonic coupling to photocapacitor biointerfaces improves safe and efficacious neuromodulating displacement charges for an average of 185% in the entire visible spectrum while maintaining the faradic currents below 1%. Hot-electron injection dominantly leads the enhancement of displacement current in the blue spectral window, and the nanoantenna effect is mainly responsible for the improvement in the red spectral region. The plasmonic photocapacitor facilitates wireless modulation of single cells at three orders of magnitude below the maximum retinal intensity levels, corresponding to one of the most sensitive optoelectronic neural interfaces. This study introduces a new way of using plasmonics for safe and effective photostimulation of neurons and paves the way toward ultrasensitive plasmon-assisted neurostimulation devices.Publication Open Access Predicting new iron garnet thin films with perpendicular magnetic anisotropy(Elsevier, 2020) N/A; Department of Electrical and Electronics Engineering; Zanjani, Saeedeh Mokarian; Onbaşlı, Mehmet Cengiz; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; N/A; 258783Magnetic iron garnets are insulators with low Gilbert damping with many applications in spintronics. Many emerging spintronic applications require perpendicular magnetic anisotropy (PMA) although garnets have only a few PMA types (i.e. terbium and samarium garnet). More and stable PMA garnet options are needed for investigating new spintronic phenomena. In this study, we predict 20 new epitaxial magnetic iron garnet film/substrate pairs with stable PMA at room temperature. The effective anisotropy energies of 10 different garnet films that are lattice-matched to 5 different commercially available garnet substrates (total 50 film/substrate pairs) have been calculated using shape, magnetoelastic and magnetocrystalline anisotropy terms. Strain type, tensile or compressive depending on substrate choice, as well as the sign and the magnitude of the magnetostriction constants of garnets determine if a garnet film may possess PMA. We show the conditions in which Samarium, Gadolinium, Terbium, Holmium, Dysprosium and Thulium garnets may possess PMA on the investigated garnet substrate types. New PMA garnet films with tunable saturation moment and field may improve spin-orbit torque memory and compensated magnonic thin film devices.Publication Open Access Spin-torque oscillation in a magnetic insulator probed by a single-spin sensor(American Physical Society (APS), 2020) Zhang, H.; Ku, M. J. H.; Casola, F.; Du, C. H.; van der Sar, T.; Ross, C. A.; Tserkovnyak, Y.; Yacoby, A.; Walsworth, R. L.; Department of Electrical and Electronics Engineering; Onbaşlı, Mehmet Cengiz; Faculty Member; Department of Electrical and Electronics Engineering; College of Engineering; 258783We locally probe the magnetic fields generated by a spin-torque oscillator (STO) in a microbar of ferrimagnetic insulator yttrium-iron-garnet using the spin of a single nitrogen-vacancy (NV) center in diamond. The combined spectral resolution and sensitivity of the NV sensor allows us to resolve multiple spin-wave modes and characterize their damping. When damping is decreased sufficiently via spin injection, the modes auto-oscillate, as indicated by a strongly reduced linewidth, a diverging magnetic power spectral density, and synchronization of the STO frequency to an external microwave source. These results open the way for quantitative, nanoscale mapping of the microwave signals generated by STOs, as well as harnessing STOs as local probes of mesoscopic spin systems.Publication Open Access Advanced solid-state lasers 2019: focus issue introduction(Optical Society of America (OSA), 2020) Goodno, Gregory; Mirov, Sergey; Nilsson, Johan; Petersen, Alan; Sorokina, Irina; Taccheo, Stefano; Department of Electrical and Electronics Engineering; Department of Physics; Sennaroğlu, Alphan; Faculty Member; Department of Electrical and Electronics Engineering; Department of Physics; Koç University Surface Science and Technology Center (KUYTAM) / Koç Üniversitesi Yüzey Teknolojileri Araştırmaları Merkezi (KUYTAM); College of Engineering; College of Sciences; 23851This joint issue of Optics Express and Optical Materials Express features 17 state-of-the art articles written by authors who participated in the international conference Advanced Solid-State Lasers held in Vienna, Austria, from September 29 to October 3, 2019. This introduction provides a summary of these articles that cover numerous areas of solid-state lasers from materials research to sources and from design to experimental demonstration.Publication Open Access Hexagonal boron nitride incorporation to achieve high performance Li4Ti5O12 electrodes(American Institute of Physics (AIP) Publishing, 2020) Department of Electrical and Electronics Engineering; Ergen, Onur; Department of Electrical and Electronics Engineering; Koç University Surface Science and Technology Center (KUYTAM) / Koç Üniversitesi Yüzey Teknolojileri Araştırmaları Merkezi (KUYTAM); College of Engineering; Graduate School of Sciences and Engineering; 272106There is an increasing demand for fast charging and high capacity lithium ion batteries. However, conventional Li-ion battery chemistries cannot meet the stringent requirements of these demands due to the poor performance of graphite anodes, especially on safety during fast charging. Finding the right anode material that can replace conventional graphite while providing high capacity is very challenging. Today, lithium titanium oxide (LTO) is considered one of the most attractive anode materials that can provide the desired ultra-fast charging ability (>10C) with high safety. However, it has many serious drawbacks when compared to the existing graphite anodes, including poor intrinsic conductivity, narrow electrochemical window, etc. Extensive research has been done to overcome these problems, especially in developing new LTO composite materials with reduced graphene oxide. However, even these methods have rapid capacity fading at high current densities, >5C, due to increased internal resistance and polarization losses. Here, we demonstrate an effective way to improve LTO composite materials by developing unique nanoengineered three-dimensional frameworks with hexagonal boron nitride (h-BN) addition. Li-ion cells with h-BN incorporation exhibit excellent performance and operational stability, especially at fast and ultra-fast charging rates, >10C.Publication Metadata only Predicting new iron garnet thin films with perpendicular magnetic anisotropy(Elsevier, 2020) Department of Electrical and Electronics Engineering; Zanjani, Saeedeh Mokarian; Onbaşlı, Mehmet Cengiz; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; N/A; 258783Magnetic iron garnets are insulators with low Gilbert damping with many applications in spintronics. Many emerging spintronic applications require perpendicular magnetic anisotropy (PMA) although garnets have only a few PMA types (i.e. terbium and samarium garnet). More and stable PMA garnet options are needed for investigating new spintronic phenomena. In this study, we predict 20 new epitaxial magnetic iron garnet film/substrate pairs with stable PMA at room temperature. The effective anisotropy energies of 10 different garnet films that are lattice-matched to 5 different commercially available garnet substrates (total 50 film/substrate pairs) have been calculated using shape, magnetoelastic and magnetocrystalline anisotropy terms. Strain type, tensile or compressive depending on substrate choice, as well as the sign and the magnitude of the magnetostriction constants of garnets determine if a garnet film may possess PMA. We show the conditions in which Samarium, Gadolinium, Terbium, Holmium, Dysprosium and Thulium garnets may possess PMA on the investigated garnet substrate types. New PMA garnet films with tunable saturation moment and field may improve spin-orbit torque memory and compensated magnonic thin film devices.Publication Open Access Cation exchange mediated synthesis of bright Au@ZnTe core-shell nanocrystals(Institute of Physics (IOP) Publishing, 2021) Şahin, Mehmet; N/A; Department of Electrical and Electronics Engineering; Sadeghi, Sadra; Melikov, Rustamzhon; Nizamoğlu, Sedat; PhD Student; PhD Student; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; N/A; N/A; 130295The synthesis of heterostructured core-shell nanocrystals has attracted significant attention due to their wide range of applications in energy, medicine and environment. To further extend the possible nanostructures, non-epitaxial growth is introduced to form heterostructures with large lattice mismatches, which cannot be achieved by classical epitaxial growth techniques. Here, we report the synthetic procedure of Au@ZnTe core-shell nanostructures by cation exchange reaction for the first time. For that, bimetallic Au@Ag heterostructures were synthesized by using PDDA as stabilizer and shape-controller. Then, by addition of Te and Zn precursors in a step-wise reaction, the zinc and silver cation exchange was performed and Au@ZnTe nanocrystals were obtained. Structural and optical characterization confirmed the formation of the Au@ZnTe nanocrystals. The optimization of the synthesis led to the bright nanocrystals with a photoluminescence quantum yield up to 27%. The non-toxic, versatile synthetic route, and bright emission of the synthesized Au@ZnTe nanocrystals offer significant potential for future bio-imaging and optoelectronic applications.Publication Open Access Quantum dot to nanorod transition for efficient white-light-emitting diodes with suppressed absorption losses(American Chemical Society (ACS), 2022) Melikov, Rustamzhon; N/A; Department of Electrical and Electronics Engineering; N/A; Önal, Asım; Sadeghi, Sadra; Karatüm, Onuralp; Nizamoğlu, Sedat; Eren, Güncem Özgün; PhD Student; Faculty Member; Department of Electrical and Electronics Engineering; College of Engineering; Graduate School of Sciences and Engineering; N/A; N/A; N/A; 130295; N/AColloidal nanocrystals have great potential for next-generation solid-state lighting due to their outstanding emission and absorption tunability via size and morphology, narrow emission linewidth, and high photoluminescence quantum yield (PLQY). However, the losses due to self-and interabsorption among multitudes of nanocrystals significantly decrease external quantum yield levels of light-emitting diodes (LEDs). Here, we demonstrate efficient white LEDs via CdSe/CdS dot to ""dot-in-rod"" transition that enabled a large Stokes shift of 780 meV and significantly reduced absorption losses when used in conjunction with near-unity PLQY ZnCdSe/ZnSe quantum dots (QDs) emitting at the green spectral range. The optimized incorporation of nanocrystals in a liquid state led to the white LEDs with an ultimate external quantum efficiency (EQE) of 42.9%, with a net increase of EQE of 10.3% in comparison with white LEDs using CdSe/CdS dots. Therefore, combinations of nanocrystals with different nanomorphologies hold high promise for efficient white LEDs.Publication Open Access Visual acuity response when using the 3D head-up display in the presence of an accommodation-convergence conflict(Taylor _ Francis, 2019) Department of Electrical and Electronics Engineering; Ürey, Hakan; Soomro, Shoaib Rehman; Faculty Member; Department of Electrical and Electronics Engineering; College of Engineering; Graduate School of Sciences and Engineering; 8579; N/AVisual discomfort and fatigue due to accommodation-convergence (AC) conflict in stereoscopic displays has been widely reported, but little is known about its impact on visual acuity, particularly when automotive three-dimensional (3D) head-up displays (HUDs) are involved. This paper presents a study on the visual acuity response when an indigenously developed 75% transparent retroreflective screen is used as a windshield 3D HUD. The simulated optical collimation technique was used to provide the virtual content at a farther depth (i.e. on the road while driving). Two user test experiments were performed. The first test was performed under the see-through condition, where the real scene (i.e. roadside view) was perceived through the 3D HUD, while the second test was performed under the simulated collimation condition, where a stereo-collimated virtual content was projected on the HUD at a farther depth. The results showed a slightly declining trend (from 20/20 to 20/25) in visual acuity response when the HUD screen was placed between the viewer and the scene. An inverse relation between the amount of AC conflict and visual acuity was observed under the simulated collimation condition. The >100 cm user-to-screen distance was found to be comfortable, providing the highest acuity response.