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Permanent URI for this collectionhttps://hdl.handle.net/20.500.14288/6
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Publication Open Access Enhanced sinterability, thermal conductivity and dielectric constant of glass-ceramics with PVA and BN additions(Multidisciplinary Digital Publishing Institute (MDPI), 2022) Akkasoğlu, Ufuk; Çiçek, Buğra; N/A; Department of Chemistry; Arıbuğa, Dilara; Balcı, Özge; Researcher; Department of Chemistry; Koç University AKKİM Boron-Based Materials _ High-technology Chemicals Research _ Application Center (KABAM) / Koç Üniversitesi AKKİM Bor Tabanlı Malzemeler ve İleri Teknoloji Kimyasallar Uygulama ve Araştırma Merkezi (KABAM); Graduate School of Sciences and Engineering; College of Sciences; N/A; 295531With the rapid development of the microelectronics industry, many efforts have been made to improve glass-ceramics' sinterability, thermal conductivity, and dielectric properties, which are essential components of electronic materials. In this study, low-alkali borosilicate glass-ceramics with PVA addition and glass-BN composites were prepared and successfully sintered at 770 degrees C. The phase composition, density, microstructure, thermal conductivity, and dielectric constant were investigated. It was shown that PVA addition contributes to the densification process of glass-ceramics (~88% relative density, with closed/open pores in the microstructure) and improves the thermal conductivity of glass material from 1.489 to 2.453 W/K.m. On the other hand, increasing BN addition improves microstructures by decreasing porosities and thus increasing relative densities. A glass-12 wt. % BN composite sample exhibited almost full densification after sintering and presented apparent and open pores of 2.6 and 0.08%, respectively. A high thermal conductivity value of 3.955 W/K.m and a low dielectric constant of 3.00 (at 5 MHz) were observed in this material. Overall, the resulting glass-ceramic samples showed dielectric constants in the range of 2.40-4.43, providing a potential candidate for various electronic applications.Publication Open Access Al-doped MgB2 materials studied using electron paramagnetic resonance and Raman spectroscopy(American Institute of Physics (AIP) Publishing, 2016) Erdem, Emre; Repp, Sergej; Weber, Stefan; N/A; Department of Chemistry; Bateni, Ali; Somer, Mehmet Suat; PhD Student; Faculty Member; Department of Chemistry; Graduate School of Sciences and Engineering; College of Sciences; N/A; 178882Undoped and aluminum (Al) doped magnesium diboride (MgB2) samples were synthesized using a high-temperature solid-state synthesis method. The microscopic defect structures of Al-doped MgB2 samples were systematically investigated using X-ray powder diffraction, Raman spectroscopy, and electron paramagnetic resonance. It was found that Mg-vacancies are responsible for defect-induced peculiarities in MgB2. Above a certain level of Al doping, enhanced conductive properties of MgB2 disappear due to filling of vacancies or trapping of Al in Mg-related vacancy sites. Published by AIP Publishing.Publication Open Access Defect structure of ultrafine MgB2 nanoparticles(American Institute of Physics (AIP) Publishing, 2014) Repp, Sergej; Thomann, Ralf; Acar, Selçuk; Erdem, Emre; N/A; Department of Chemistry; Bateni, Ali; Somer, Mehmet Suat; PhD Student; Faculty Member; Department of Chemistry; Graduate School of Sciences and Engineering; College of Sciences; N/A; 178882Defect structure of MgB2 bulk and ultrafine particles, synthesized by solid state reaction route, have been investigated mainly by the aid of X-band electron paramagnetic resonance spectrometer. Two different amorphous Boron (B) precursors were used for the synthesis of MgB2, namely, boron 95 (purity 95%-97%, <1.5 mu m) and nanoboron (purity >98.5%, <250 nm), which revealed bulk and nanosized MgB2, respectively. Scanning and transmission electron microscopy analysis demonstrate uniform and ultrafine morphology for nanosized MgB2 in comparison with bulk MgB2. Powder X-ray diffraction data show that the concentration of the by-product MgO is significantly reduced when nanoboron is employed as precursor. It is observed that a significant average particle size reduction for MgB2 can be achieved only by using B particles of micron or nano size. The origin and the role of defect centers were also investigated and the results proved that at nanoscale MgB2 material contains Mg vacancies. Such vacancies influence the connectivity and the conductivity properties which are crucial for the superconductivity applications. (C) 2014 AIP Publishing LLC.Publication Open Access Impact of rehabilitation on fatigue in post-Covid-19 patients: a systematic review and meta-analysis(Multidisciplinary Digital Publishing Institute (MDPI), 2022) de Sire, Alessandro; Moggio, Lucrezia; Marotta, Nicola; Agostini, Francesco; Tasselli, Anna; Ferrante, Vera Drago; Curci, Claudio; Calafiore, Dario; Ferraro, Francesco; Bernetti, Andrea; Ammendolia, Antonio; Taşkıran, Özden Özyemişçi; Faculty Member; School of Medicine; 133091The post-COVID-19 syndrome may affect patients after the COVID-19 post-acute phase. In particular, the 69% of patients reported persistent fatigue at the discharge. To date, no clear data are available regarding the most effective rehabilitative approaches for the treatment of this condition. Thus, this systematic review aimed to evaluate the rehabilitation treatment's efficacy on fatigue in post-COVID-19 patients. We systematically searched PubMed, Scopus, and Web of Science databases to find longitudinal study designs presenting: post-COVID-19 patients as participants; a rehabilitative approach aimed to reduce post-COVID-19 syndrome as intervention; and fatigue intensity assessed through an evaluation tool that quantified the perceived exertion (i.e., fatigue severity scale, FSS; Borg Scale (BS); Borg Category Ratio 10, CR10; Checklist Individual Strength (CIS) fatigue scale; FACIT (Functional Assessment of Chronic Illness Therapy) fatigue scale). The present systematic review protocol was registered on PROSPERO (registration number CRD42021284058). Out of 704 articles, 6 studies were included. Nearly all patients showed COVID-19-related fatigue, and after the rehabilitation treatment, only 17% of subjects reported the persistency of symptoms. The overall effect size reported a -1.40 decrease in Borg Category Ratio 10 with a SE of 0.05 and a 95% CI between -1.50 and -1.30 (p < 0.001). The present systematic review and meta-analysis underlines the rehabilitation role in the fatigue reduction in patients affected by post-COVID-19 syndrome.Publication Open Access Optimum folding pathways of proteins: their determination and properties(American Institute of Physics (AIP) Publishing, 2006) Department of Chemical and Biological Engineering; Güner, Pınar Tatar; Arkun, Yaman; Erman, Burak; Teaching Faculty; Faculty Member; Faculty Member; Department of Chemical and Biological Engineering; College of Engineering; 188227; 108526; 179997We develop a dynamic optimization technique for determining optimum folding pathways of proteins starting from different initial configurations. A coarse-grained Go model is used. Forces acting on each bead are (i) the friction force, (ii) forces from bond length constraints, (iii) excluded volume constraints, and (iv) attractive forces between residue pairs that are in contact in the native state. An objective function is defined as the total attractive energy between nonbonded residues, which are neighbors in the native state. The objective function is minimized over all feasible paths, satisfying bond length and excluded volume constraints. The optimization problem is nonconvex and contains a large number of constraints. An augmented Lagrangian method with a penalty barrier function was used to solve the problem. The method is applied to a 36-residue protein, chicken villin headpiece. Sequences of events during folding of the protein are determined for various pathways and analyzed. The relative time scales are compared and scaled according to experimentally measured events. Formation times of the helices, turn, and the loop agree with experimental data. We obtain the overall folding time of the protein in the range of 600 ns-1.2 mu s that is smaller than the experimental result of 4-5 mu s, showing that the optimal folding times that we obtain may be possible lower bounds. Time dependent variables during folding and energies associated with short- and long-range interactions between secondary structures are analyzed in modal space using Karhunen-Loeve expansion.Publication Open Access Collective excitations of a laser driven atomic condensate in an optical cavity(Maik Nauka/Interperiodica Publishing, 2013) Öztop, B.; Türeci, H. E.; Department of Physics; Müstecaplıoğlu, Özgür Esat; Faculty Member; Department of Physics; College of Sciences; 1674We theoretically examine collective excitations of an optically driven atomic Bose-Einstein condensate, coupled to a high-finesse optical cavity. This open system has been recently used for the experimental demonstration of the Dicke superradiance of cavity photons, which is simultaneously and mutually triggered by spontaneous breaking of translational symmetry of the condensate into a crystalline order. We first develop a Hartree-Fock mean field dynamical model of the physical system. Using this model, we compute the dynamics of the cavity photons, the condensate density profile and the Dicke phase transition diagram. Both the imaginary-time and real-time evolution methods are used in the calculations. Collective excitations are determined by the solving Bogoliubov-de Gennes equations. The spectrum, softening of the modes and energetic hierarchy of excitations are determined.Publication Open Access Phase noise in oscillators as differential-algebraic systems with colored noise sources(Society of Photo-optical Instrumentation Engineers (SPIE), 2004) Department of Electrical and Electronics Engineering; Demir, Alper; Faculty Member; Department of Electrical and Electronics Engineering; College of Engineering; 3756Oscillators are key components of many kinds of systems, particularly electronic and opto-electronic systems. Undesired perturbations, i.e. noise, in practical systems adversely affect the spectral and timing properties of the signals generated by oscillators resulting in phase noise and timing jitter, which are key performance limiting factors, being major contributors to bit-error-rate (BER) of RF and possibly optical communication systems, and creating synchronization problems in clocked and sampled-data electronic systems. In this paper. we review our work on the theory and numerical methods for nonlinear perturbation and noise analysis of oscillators described by a system of differential-algebraic equations (DAEs) with white and colored noise sources. The bulk of the work reviewed in this paper first appeared in [1], then in [2] and [3]. Prior to the work mentioned above, we developed a theory and numerical methods for nonlinear perturbation and noise analysis of oscillators described by a system of ordinary differential equations (ODEs) with white noise sources only [4, 5]. In this paper, we also discuss some open problems and issues in the modeling and analysis of phase noise both in free running oscillators and in phase/injection-locked ones.Publication Open Access Modeling and experimental observation of parametric processes in segmented KTiOPO4 channel waveguides(American Institute of Physics (AIP) Publishing, 1999) Aschieri, P.; Baldi, P.; Bierlein, J.; Department of Physics; Sundheimer, Michael; Faculty Member; Department of Physics; College of SciencesThis letter presents a modeling technique for quasiphase-matched parametric processes in segmented channel waveguides and the results of measurements of infrared parametric fluorescence in segmented KTiOPO4 channel waveguides. We demonstrate both theoretically and experimentally a strong dependence of optical parametric oscillator tuning curves and parametric conversion efficiency (parametric gain) on the segmentation duty cycle. We show that the optimum conversion efficiency for parametric interactions in segmented waveguides is obtained for duty cycles greater than 50%. Our results validate the use of an effective continuous waveguide model for segmented channel waveguide calculations over a wide range of wavelengths and duty cycles. (C) 1999 American Institute of Physics. [S0003-6951(99)02812-0].Publication Open Access Top-down technique for scaling to nano in silicon MEMS(American Vacuum Society (AVS), 2017) Wollschlaeger, Nicole; Oesterle, Werner; Leblebici, Yusuf; Department of Mechanical Engineering; Alaca, Burhanettin Erdem; Nadar, Gökhan; Yılmaz, Mustafa Akın; Kılınç, Yasin; Taşdemir, Zuhal; Faculty Member; PhD Student; PhD Student; Department of Mechanical Engineering; Koç University Surface Science and Technology Center (KUYTAM) / Koç Üniversitesi Yüzey Teknolojileri Araştırmaları Merkezi (KUYTAM); Graduate School of Sciences and Engineering; 115108; N/A; N/A; N/A; N/ANanoscale building blocks impart added functionalities to microelectromechanical systems (MEMS). The integration of silicon nanowires with MEMS-based sensors leading to miniaturization with improved sensitivity and higher noise immunity is one example highlighting the advantages of this multiscale approach. The accelerated pace of research in this area gives rise to an urgent need for batch-compatible solutions for scaling to nano. To address this challenge, a monolithic fabrication approach of silicon nanowires with 10-mu m-thick silicon-on-insulator (SOI) MEMS is developed in this work. A two-step Si etching approach is adopted, where the first step creates a shallow surface protrusion and the second step releases it in the form of a nanowire. It is during this second deep etching step that MEMS-with at least a 2-order-of-magnitude scale difference-is formed as well. The technique provides a pathway for preserving the lithographic resolution and transforming it into a very high mechanical precision in the assembly of micro-and nanoscales with an extreme topography. Validation of the success of integration is carried out via in situ actuation of MEMS inside an electron microscope loading the nanowire up to its fracture. The technique yields nanowires on the top surface of MEMS, thereby providing ease of access for the purposes of carrying out surface processes such as doping and contact formation as well as in situ observation. As the first study demonstrating such monolithic integration in thick SOI, the work presents a pathway for scaling down to nano for future MEMS combining multiple scales.Publication Open Access Optimization of room-temperature continuous-wave cr (4+)-Doped solid-state lasers: experiment and modeling(Institute of Electrical and Electronics Engineers (IEEE), 2001) Department of Physics; Sennaroğlu, Alphan; Faculty Member; Department of Physics; College of Sciences; 23851A novel study to determine the optimum crystal and resonator parameters for Cr4+ doped lasers subjected to lifetime thermal loading was permormed. The comparison of the results of lasing threshold, pump absorption saturation, and power efficiency measurements was done with the predictions of a theoretical model to determine the laser cross sections. Using the best-fit cross-section values, numerical optimization studies were carried out to determine the optimum crystal absorption, resonator reflectivity, and crystal length which maximized the output power.