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Permanent URI for this collectionhttps://hdl.handle.net/20.500.14288/6
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Publication Open Access Al-doped MgB2 materials studied using electron paramagnetic resonance and Raman spectroscopy(American Institute of Physics (AIP) Publishing, 2016) Erdem, Emre; Repp, Sergej; Weber, Stefan; N/A; Department of Chemistry; Bateni, Ali; Somer, Mehmet Suat; PhD Student; Faculty Member; Department of Chemistry; Graduate School of Sciences and Engineering; College of Sciences; N/A; 178882Undoped and aluminum (Al) doped magnesium diboride (MgB2) samples were synthesized using a high-temperature solid-state synthesis method. The microscopic defect structures of Al-doped MgB2 samples were systematically investigated using X-ray powder diffraction, Raman spectroscopy, and electron paramagnetic resonance. It was found that Mg-vacancies are responsible for defect-induced peculiarities in MgB2. Above a certain level of Al doping, enhanced conductive properties of MgB2 disappear due to filling of vacancies or trapping of Al in Mg-related vacancy sites. Published by AIP Publishing.Publication Open Access Defect structure of ultrafine MgB2 nanoparticles(American Institute of Physics (AIP) Publishing, 2014) Repp, Sergej; Thomann, Ralf; Acar, Selçuk; Erdem, Emre; N/A; Department of Chemistry; Bateni, Ali; Somer, Mehmet Suat; PhD Student; Faculty Member; Department of Chemistry; Graduate School of Sciences and Engineering; College of Sciences; N/A; 178882Defect structure of MgB2 bulk and ultrafine particles, synthesized by solid state reaction route, have been investigated mainly by the aid of X-band electron paramagnetic resonance spectrometer. Two different amorphous Boron (B) precursors were used for the synthesis of MgB2, namely, boron 95 (purity 95%-97%, <1.5 mu m) and nanoboron (purity >98.5%, <250 nm), which revealed bulk and nanosized MgB2, respectively. Scanning and transmission electron microscopy analysis demonstrate uniform and ultrafine morphology for nanosized MgB2 in comparison with bulk MgB2. Powder X-ray diffraction data show that the concentration of the by-product MgO is significantly reduced when nanoboron is employed as precursor. It is observed that a significant average particle size reduction for MgB2 can be achieved only by using B particles of micron or nano size. The origin and the role of defect centers were also investigated and the results proved that at nanoscale MgB2 material contains Mg vacancies. Such vacancies influence the connectivity and the conductivity properties which are crucial for the superconductivity applications. (C) 2014 AIP Publishing LLC.Publication Open Access Modeling and experimental observation of parametric processes in segmented KTiOPO4 channel waveguides(American Institute of Physics (AIP) Publishing, 1999) Aschieri, P.; Baldi, P.; Bierlein, J.; Department of Physics; Sundheimer, Michael; Faculty Member; Department of Physics; College of SciencesThis letter presents a modeling technique for quasiphase-matched parametric processes in segmented channel waveguides and the results of measurements of infrared parametric fluorescence in segmented KTiOPO4 channel waveguides. We demonstrate both theoretically and experimentally a strong dependence of optical parametric oscillator tuning curves and parametric conversion efficiency (parametric gain) on the segmentation duty cycle. We show that the optimum conversion efficiency for parametric interactions in segmented waveguides is obtained for duty cycles greater than 50%. Our results validate the use of an effective continuous waveguide model for segmented channel waveguide calculations over a wide range of wavelengths and duty cycles. (C) 1999 American Institute of Physics. [S0003-6951(99)02812-0].Publication Open Access Controlled photoluminescence in amorphous-silicon-nitride microcavities(American Institute of Physics (AIP) Publishing, 2001) Tanrıseven, S.; Department of Physics; Serpengüzel, Ali; Faculty Member; Department of Physics; College of Sciences; 27855Narrow-band and enhanced photoluminescence have been observed in hydrogenated amorphous-silicon-nitride microcavities. The distributed Bragg reflectors were fabricated using alternating layers of hydrogenated amorphous-silicon nitride and hydrogenated amorphous-silicon oxide. The microcavity resonance wavelength was designed to be at the maximum of the bulk hydrogenated amorphous-silicon-nitride luminescence spectrum. At the microcavity resonance, the photoluminescence amplitude is enhanced, while the photoluminescence linewidth is reduced with respect to the bulk hydrogenated amorphous-silicon nitride. (C) 2001 American Institute of Physics.Publication Open Access Electron paramagnetic resonance and Raman spectroscopy studies on carbon-doped MgB2 superconductor nanomaterials(American Institute of Physics (AIP) Publishing, 2015) Erdem, Emre; Repp, Sergej; Acar, Selçuk; Kokal, İlkin; Haessler, Wolfgang; Weber, Stefan; N/A; Department of Chemistry; Bateni, Ali; Somer, Mehmet Suat; PhD Student; Faculty Member; Department of Chemistry; Graduate School of Sciences and Engineering; College of Sciences; N/A; 178882Undoped and carbon-doped magnesium diboride (MgB2) samples were synthesized using two sets of mixtures prepared from the precursors, amorphous nanoboron, and as-received amorphous carbon-doped nanoboron. The microscopic defect structures of carbon-doped MgB2 samples were systematically investigated using X-ray powder diffraction, Raman and electron paramagnetic resonance spectroscopy. Mg vacancies and C-related dangling-bond active centers could be distinguished, and sp(3)-hybridized carbon radicals were detected. A strong reduction in the critical temperature T-c was observed due to defects and crystal distortion. The symmetry effect of the latter is also reflected on the vibrational modes in the Raman spectra. (C) 2015 AIP Publishing LLC.Publication Open Access Spectral tuning of liquid microdroplets standing on a superhydrophobic surface using electrowetting(American Institute of Physics (AIP) Publishing, 2008) Department of Physics; Kiraz, Alper; Karadağ, Yasin; Coşkun, Ahmet Faruk; Faculty Member; PhD Student; Department of Physics; College of Sciences; 22542; N/A; N/AUsing electrowetting, we demonstrate reversible spectral tuning of the whispering gallery modes of glycerol/water microdroplets standing on a superhydrophobic surface by up to 4.7 nm at 400 V. Our results can inspire electrically tunable optical switches and filters based on microdroplets on a superhydrophobic surface. The sensitivity of the observed spectral drift to the contact angle can also be used to measure the contact angles of microdroplets on a superhydrophobic surface. (C) 2008 American Institute of Physics.Publication Open Access Guided self-assembly of metallic nanowires and channels(American Institute of Physics (AIP) Publishing, 2004) Şehitoğlu, Hüseyin; Saif, Taher; Department of Mechanical Engineering; Alaca, Burhanettin Erdem; Faculty Member; Department of Mechanical Engineering; College of Engineering; 115108A method is presented to form metallic nanowires and nanochannels by guided self-assembly. The method relies on an initial plasma-enhanced chemical vapor deposition of a silicon oxide film with altered chemistry on a silicon wafer, and the cracking of the film due to tensile stresses upon annealing. The fabricated stress concentration features on the Si substrate control the number of cracks and their orientation. These cracks are then filled with electroless nickel, and the subsequent removal of SiO2 produces a controlled network of nanowires of about 100 nm in dimension. In addition to nanowires, nanobridges, and nanocantilevers have also been fabricated by releasing the wires, confirming that the resulting structures are rather robust. (C) 2004 American Institute of Physics.Publication Open Access Large spectral tuning of liquid microdroplets standing on a superhydrophobic surface using optical scattering force(American Institute of Physics (AIP) Publishing, 2007) Department of Physics; Kiraz, Alper; Karadağ, Yasin; Kurt, Adnan; Sennaroğlu, Alphan; Çankaya, Hüseyin; Faculty Member; PhD Student; Teaching Faculty; Faculty Member; Researcher; Department of Physics; College of Sciences; 22542; N/A; N/A; 194455; 23851; N/AWe demonstrate large spectral tuning of glycerol/water microdroplets standing on a superhydrophobic surface using the optical scattering force exerted by a 1064 nm Nd(3+):YVO(4) solid-state laser. Spectral tuning up to 30 nm is presented in the whispering gallery modes as a result of the deformation of the microdroplets toward a truncated prolate spheroid geometry. Observed large spectral tuning is also reported to be highly reversible. This demonstration can inspire novel, largely tunable optical switches or filters based on liquid microdroplets kept in a sealed chamber.Publication Open Access Glioma-on-a-chip models(Multidisciplinary Digital Publishing Institute (MDPI), 2021) İlçi, İrem Sultan; Department of Mechanical Engineering; N/A; N/A; Önder, Tuğba Bağcı; Taşoğlu, Savaş; Üstün, Merve; Dabbagh, Sajjad Rahmani; Faculty Member; Department of Mechanical Engineering; KU Arçelik Research Center for Creative Industries (KUAR) / KU Arçelik Yaratıcı Endüstriler Uygulama ve Araştırma Merkezi (KUAR); Koç University Research Center for Translational Medicine (KUTTAM) / Koç Üniversitesi Translasyonel Tıp Araştırma Merkezi (KUTTAM); School of Medicine; College of Engineering; Graduate School of Sciences and Engineering; Graduate School of Social Sciences and Humanities; 184359; 291971; N/A; N/AGlioma, as an aggressive type of cancer, accounts for virtually 80% of malignant brain tumors. Despite advances in therapeutic approaches, the long-term survival of glioma patients is poor (it is usually fatal within 12-14 months). Glioma-on-chip platforms, with continuous perfusion, mimic in vivo metabolic functions of cancer cells for analytical purposes. This offers an unprecedented opportunity for understanding the underlying reasons that arise glioma, determining the most effective radiotherapy approach, testing different drug combinations, and screening conceivable side effects of drugs on other organs. Glioma-on-chip technologies can ultimately enhance the efficacy of treatments, promote the survival rate of patients, and pave a path for personalized medicine. In this perspective paper, we briefly review the latest developments of glioma-on-chip technologies, such as therapy applications, drug screening, and cell behavior studies, and discuss the current challenges as well as future research directions in this field.Publication Open Access Spectral self-interference fluorescence microscopy(American Institute of Physics (AIP) Publishing, 2004) Moiseev, L.; Cantor, C. R.; Doğan, M.; Goldberg, B. B.; Swan, A. K.; Ünlü, M. S.; Department of Electrical and Electronics Engineering; Aksun, M. İrşadi; Faculty Member; Department of Electrical and Electronics Engineering; College of Engineering; 28358Spontaneous emission of fluorophores located close to a reflecting surface is modified by the interference between direct and reflected waves. The spectral patterns of fluorescent emission near reflecting surfaces can be precisely described with a classical model that considers the relative intensity and polarization state of direct and reflected waves depending on dipole orientation. An algorithm based on the emission model and polynomial fitting built into a software application can be used for fast and efficient analysis of self-interference spectra, yielding information about the location of the emitters with subnanometer precision. Spectral information was used to study thin films of fluorescent substances on surfaces.