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Publication Open Access Enhanced sinterability, thermal conductivity and dielectric constant of glass-ceramics with PVA and BN additions(Multidisciplinary Digital Publishing Institute (MDPI), 2022) Akkasoğlu, Ufuk; Çiçek, Buğra; N/A; Department of Chemistry; Arıbuğa, Dilara; Balcı, Özge; Researcher; Department of Chemistry; Koç University AKKİM Boron-Based Materials _ High-technology Chemicals Research _ Application Center (KABAM) / Koç Üniversitesi AKKİM Bor Tabanlı Malzemeler ve İleri Teknoloji Kimyasallar Uygulama ve Araştırma Merkezi (KABAM); Graduate School of Sciences and Engineering; College of Sciences; N/A; 295531With the rapid development of the microelectronics industry, many efforts have been made to improve glass-ceramics' sinterability, thermal conductivity, and dielectric properties, which are essential components of electronic materials. In this study, low-alkali borosilicate glass-ceramics with PVA addition and glass-BN composites were prepared and successfully sintered at 770 degrees C. The phase composition, density, microstructure, thermal conductivity, and dielectric constant were investigated. It was shown that PVA addition contributes to the densification process of glass-ceramics (~88% relative density, with closed/open pores in the microstructure) and improves the thermal conductivity of glass material from 1.489 to 2.453 W/K.m. On the other hand, increasing BN addition improves microstructures by decreasing porosities and thus increasing relative densities. A glass-12 wt. % BN composite sample exhibited almost full densification after sintering and presented apparent and open pores of 2.6 and 0.08%, respectively. A high thermal conductivity value of 3.955 W/K.m and a low dielectric constant of 3.00 (at 5 MHz) were observed in this material. Overall, the resulting glass-ceramic samples showed dielectric constants in the range of 2.40-4.43, providing a potential candidate for various electronic applications.Publication Open Access Al-doped MgB2 materials studied using electron paramagnetic resonance and Raman spectroscopy(American Institute of Physics (AIP) Publishing, 2016) Erdem, Emre; Repp, Sergej; Weber, Stefan; N/A; Department of Chemistry; Bateni, Ali; Somer, Mehmet Suat; PhD Student; Faculty Member; Department of Chemistry; Graduate School of Sciences and Engineering; College of Sciences; N/A; 178882Undoped and aluminum (Al) doped magnesium diboride (MgB2) samples were synthesized using a high-temperature solid-state synthesis method. The microscopic defect structures of Al-doped MgB2 samples were systematically investigated using X-ray powder diffraction, Raman spectroscopy, and electron paramagnetic resonance. It was found that Mg-vacancies are responsible for defect-induced peculiarities in MgB2. Above a certain level of Al doping, enhanced conductive properties of MgB2 disappear due to filling of vacancies or trapping of Al in Mg-related vacancy sites. Published by AIP Publishing.Publication Open Access Defect structure of ultrafine MgB2 nanoparticles(American Institute of Physics (AIP) Publishing, 2014) Repp, Sergej; Thomann, Ralf; Acar, Selçuk; Erdem, Emre; N/A; Department of Chemistry; Bateni, Ali; Somer, Mehmet Suat; PhD Student; Faculty Member; Department of Chemistry; Graduate School of Sciences and Engineering; College of Sciences; N/A; 178882Defect structure of MgB2 bulk and ultrafine particles, synthesized by solid state reaction route, have been investigated mainly by the aid of X-band electron paramagnetic resonance spectrometer. Two different amorphous Boron (B) precursors were used for the synthesis of MgB2, namely, boron 95 (purity 95%-97%, <1.5 mu m) and nanoboron (purity >98.5%, <250 nm), which revealed bulk and nanosized MgB2, respectively. Scanning and transmission electron microscopy analysis demonstrate uniform and ultrafine morphology for nanosized MgB2 in comparison with bulk MgB2. Powder X-ray diffraction data show that the concentration of the by-product MgO is significantly reduced when nanoboron is employed as precursor. It is observed that a significant average particle size reduction for MgB2 can be achieved only by using B particles of micron or nano size. The origin and the role of defect centers were also investigated and the results proved that at nanoscale MgB2 material contains Mg vacancies. Such vacancies influence the connectivity and the conductivity properties which are crucial for the superconductivity applications. (C) 2014 AIP Publishing LLC.Publication Open Access Impact of rehabilitation on fatigue in post-Covid-19 patients: a systematic review and meta-analysis(Multidisciplinary Digital Publishing Institute (MDPI), 2022) de Sire, Alessandro; Moggio, Lucrezia; Marotta, Nicola; Agostini, Francesco; Tasselli, Anna; Ferrante, Vera Drago; Curci, Claudio; Calafiore, Dario; Ferraro, Francesco; Bernetti, Andrea; Ammendolia, Antonio; Taşkıran, Özden Özyemişçi; Faculty Member; School of Medicine; 133091The post-COVID-19 syndrome may affect patients after the COVID-19 post-acute phase. In particular, the 69% of patients reported persistent fatigue at the discharge. To date, no clear data are available regarding the most effective rehabilitative approaches for the treatment of this condition. Thus, this systematic review aimed to evaluate the rehabilitation treatment's efficacy on fatigue in post-COVID-19 patients. We systematically searched PubMed, Scopus, and Web of Science databases to find longitudinal study designs presenting: post-COVID-19 patients as participants; a rehabilitative approach aimed to reduce post-COVID-19 syndrome as intervention; and fatigue intensity assessed through an evaluation tool that quantified the perceived exertion (i.e., fatigue severity scale, FSS; Borg Scale (BS); Borg Category Ratio 10, CR10; Checklist Individual Strength (CIS) fatigue scale; FACIT (Functional Assessment of Chronic Illness Therapy) fatigue scale). The present systematic review protocol was registered on PROSPERO (registration number CRD42021284058). Out of 704 articles, 6 studies were included. Nearly all patients showed COVID-19-related fatigue, and after the rehabilitation treatment, only 17% of subjects reported the persistency of symptoms. The overall effect size reported a -1.40 decrease in Borg Category Ratio 10 with a SE of 0.05 and a 95% CI between -1.50 and -1.30 (p < 0.001). The present systematic review and meta-analysis underlines the rehabilitation role in the fatigue reduction in patients affected by post-COVID-19 syndrome.Publication Open Access Phase noise in oscillators as differential-algebraic systems with colored noise sources(Society of Photo-optical Instrumentation Engineers (SPIE), 2004) Department of Electrical and Electronics Engineering; Demir, Alper; Faculty Member; Department of Electrical and Electronics Engineering; College of Engineering; 3756Oscillators are key components of many kinds of systems, particularly electronic and opto-electronic systems. Undesired perturbations, i.e. noise, in practical systems adversely affect the spectral and timing properties of the signals generated by oscillators resulting in phase noise and timing jitter, which are key performance limiting factors, being major contributors to bit-error-rate (BER) of RF and possibly optical communication systems, and creating synchronization problems in clocked and sampled-data electronic systems. In this paper. we review our work on the theory and numerical methods for nonlinear perturbation and noise analysis of oscillators described by a system of differential-algebraic equations (DAEs) with white and colored noise sources. The bulk of the work reviewed in this paper first appeared in [1], then in [2] and [3]. Prior to the work mentioned above, we developed a theory and numerical methods for nonlinear perturbation and noise analysis of oscillators described by a system of ordinary differential equations (ODEs) with white noise sources only [4, 5]. In this paper, we also discuss some open problems and issues in the modeling and analysis of phase noise both in free running oscillators and in phase/injection-locked ones.Publication Open Access Modeling and experimental observation of parametric processes in segmented KTiOPO4 channel waveguides(American Institute of Physics (AIP) Publishing, 1999) Aschieri, P.; Baldi, P.; Bierlein, J.; Department of Physics; Sundheimer, Michael; Faculty Member; Department of Physics; College of SciencesThis letter presents a modeling technique for quasiphase-matched parametric processes in segmented channel waveguides and the results of measurements of infrared parametric fluorescence in segmented KTiOPO4 channel waveguides. We demonstrate both theoretically and experimentally a strong dependence of optical parametric oscillator tuning curves and parametric conversion efficiency (parametric gain) on the segmentation duty cycle. We show that the optimum conversion efficiency for parametric interactions in segmented waveguides is obtained for duty cycles greater than 50%. Our results validate the use of an effective continuous waveguide model for segmented channel waveguide calculations over a wide range of wavelengths and duty cycles. (C) 1999 American Institute of Physics. [S0003-6951(99)02812-0].Publication Open Access Optimization of room-temperature continuous-wave cr (4+)-Doped solid-state lasers: experiment and modeling(Institute of Electrical and Electronics Engineers (IEEE), 2001) Department of Physics; Sennaroğlu, Alphan; Faculty Member; Department of Physics; College of Sciences; 23851A novel study to determine the optimum crystal and resonator parameters for Cr4+ doped lasers subjected to lifetime thermal loading was permormed. The comparison of the results of lasing threshold, pump absorption saturation, and power efficiency measurements was done with the predictions of a theoretical model to determine the laser cross sections. Using the best-fit cross-section values, numerical optimization studies were carried out to determine the optimum crystal absorption, resonator reflectivity, and crystal length which maximized the output power.Publication Open Access Tunable integrated optical filters based on sapphire microspheres and liquid crystals(Society of Photo-optical Instrumentation Engineers (SPIE), 2010) Gilardi, Giovanni; Yılmaz, Hasan; Sharif, Murib Mohammed; Asquini, Rita; D'Alessandro, Antonio; Beccherelli, Romeo; Department of Physics; Sennaroğlu, Alphan; Faculty Member; Department of Physics; College of Sciences; 23851We present an integrated optical narrowband electrically tunable filter based on the whispering gallery modes of sapphire microspheres and double ion-exchanged channel BK7 glass waveguides. Tuning is provided by a liquid crystal infiltrated between the spheres and the glass substrate. By suitably choosing the radii of the spheres and of the circular apertures, upon which the spheres are positioned, arrays of different filters can be realized on the same substrate with a low cost industrial process. We evaluate the performance in terms of quality factor, mode spacing, and tuning range by comparing the numerical results obtained by the numerical finite element modeling approach and with the analytical approach of the Generalized Lorenz-Mie Theory for various design parameters. By reorienting the LC in an external electrical field, we demonstrate the tuning of the spectral response of the sapphire microsphere based filter. We find that the value of the mode spacing remains nearly unchanged for the different values of the applied electric field. An increase of the applied electric field strength, changes the refractive index of the liquid crystal, so that for a fixed geometry the mode spacing remains unchanged.Publication Open Access Controlled photoluminescence in amorphous-silicon-nitride microcavities(American Institute of Physics (AIP) Publishing, 2001) Tanrıseven, S.; Department of Physics; Serpengüzel, Ali; Faculty Member; Department of Physics; College of Sciences; 27855Narrow-band and enhanced photoluminescence have been observed in hydrogenated amorphous-silicon-nitride microcavities. The distributed Bragg reflectors were fabricated using alternating layers of hydrogenated amorphous-silicon nitride and hydrogenated amorphous-silicon oxide. The microcavity resonance wavelength was designed to be at the maximum of the bulk hydrogenated amorphous-silicon-nitride luminescence spectrum. At the microcavity resonance, the photoluminescence amplitude is enhanced, while the photoluminescence linewidth is reduced with respect to the bulk hydrogenated amorphous-silicon nitride. (C) 2001 American Institute of Physics.Publication Open Access Optimal reduced dimensional representation of classical molecular dynamics(American Institute of Physics (AIP) Publishing, 2003) Dey, Bijoy K.; Rabitz, H.; Department of Mathematics; Aşkar, Attila; Faculty Member; Department of Mathematics; College of Sciences; 178822An optimal reduced space method for capturing the low-frequency motion in classical molecular dynamics calculations is presented. This technique provides a systematic means for carrying out reduced-dimensional calculations in an effective set of reduced coordinates. The method prescribes an optimal reduced subspace linear transformation for the low frequency motion. The method is illustrated with a dynamics calculation for a model potential, where the original six-dimensional space is reduced to two (three) dimensions, depending on the desired frequency cutoff value.