Researcher: Gördeslioğlu, Mehmet
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Gördeslioğlu, Mehmet
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Publication Metadata only Theoretical study of vibrational spectroscopy of segmented poly(etherurethanes)(Amer Chemical Soc, 2000) N/A; Department of Chemistry; Department of Chemistry; Department of Chemistry; Gördeslioğlu, Mehmet; Yılgör, Emel; Yurtsever, İsmail Ersin; Undergraduate Student; Researcher; Faculty Member; College of Sciences; College of Sciences; College of Sciences; N/A; N/A; 7129N/APublication Metadata only New model for the microphase morphology of segmented polyurethanes and polyureas(Amer Chemical Soc, 2001) Department of Chemistry; Department of Chemistry; N/A; N/A; N/A; Department of Chemistry; Department of Chemistry; Yılgör, İskender; Yılgör, Emel; Ünal, Serkan; Makal, Ümit; Gördeslioğlu, Mehmet; Yurtsever, İsmail Ersin; Faculty Member; Researcher; Undergraduate Student; Undergraduate Student; Undergraduate Student; Faculty Member; College of Sciences; College of Sciences; College of Sciences; College of Sciences; College of Sciences; College of Sciences; 24181; N/A; 241611; N/A; N/A; 7129N/APublication Metadata only Studies on understanding the extent of hydrogen bonding between urethane, urea, and polyether segments: comparison of experimental results and quantum mechanical calculations.(American Chemical Society (ACS), 2000) Department of Chemistry; N/A; N/A; Department of Chemistry; Department of Chemistry; Yılgör, Emel; Metin, Burak; Gördeslioğlu, Mehmet; Yılgör, İskender; Researcher; Undergraduate Student; Undergraduate Student; Faculty Member; College of Sciences; College of Sciences; College of Sciences; College of Sciences; N/A; N/A; N/A; 24181The extent of hydrogen bonding between urethane and urea hard segments and polyether soft segments was studied using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. Model urethane and urea compounds were prepared and characterized. These models were then blended with polyether oligomers at different ratios. The change in melting peaks in both positions and enthalpies were used to measure the extent of hydrogen bonding in these systems. The DSC scans were compared with FTIR observation and also with quantum mechanical calculations.Publication Metadata only Spectroscopic, thermal, and mechanical properties of silicone-urea copolymers doped with transition metal salts(American Chemical Society (ACS), 2001) Department of Chemistry; N/A; N/A; Department of Chemistry; N/A; Department of Chemistry; Yılgör, Emel; Gördeslioğlu, Mehmet; Dizman, Bekir; Yılgör, İskender; Kaya, Ethem; Researcher; Undergraduate Student; Undergraduate Student; Faculty Member; Undergraduate Student; College of Sciences; College of Sciences; College of Sciences; College of Sciences; College of Sciences; N/A; N/A; N/A; 24181; N/AN/APublication Metadata only Studies on understanding the extent of hydrogen bonding between urethane, urea and polyether segments. Comparison of experimental results and quantum mechanical calculations(American Chemical Society (ACS), 2000) Department of Chemistry; Department of Chemistry; Department of Chemistry; Department of Chemistry; Department of Chemistry; Yılgör, Emel; Yılgör, İskender; Gördeslioğlu, Mehmet; Burak, Metin; Researcher; Faculty Member; Undergraduate Student; Undergraduate Student; College of Sciences; College of Sciences; College of Sciences; College of Sciences; 40527; 24181; N/A; N/AThe extent of hydrogen bonding between urethane and urea hard segments and polyether soft segments was studied using differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. Model urethane and urea compounds were prepared and characterized. These models were then blended with polyether oligomers at different ratios. The change in melting peaks in both positions and enthalpies were used to measure the extent of hydrogen bonding in these systems. The DSC scans were compared with FTIR observation and also with quantum mechanical calculations.Publication Metadata only Theoretical study of vibrational spectroscopy of segmented poly(etherurethanes)(American Chemical Society (ACS), 2000) Department of Chemistry; Department of Chemistry; Department of Chemistry; Department of Chemistry; Yılgör, İskender; Yurtsever, İsmail Ersin; Gördeslioğlu, Mehmet; Faculty Member; Faculty Member; Undergraduate Student; College of Sciences; College of Sciences; College of Sciences; 24181; 7129; N/AThe presence of the hydrogen bonding between model urethane, ether and alcohol compounds were studied using quantum mechanical methods. Various conformations of hydrogen bonded pairs were obtained. The relative stability of model compounds with respect to their monomers was used as the basis of detecting hydrogen bonds. The relative shifts of the infrared absorptions of functional groups upon the formation of hydrogen bonds were observed in all structures. Thus, the quantum mechanical calculations can be a powerful tool for detecting hydrogen bonds in polymers.Publication Metadata only Preparation and properties of silicone-urea copolymers doped with cobalt(II) chloride(American Chemical Society (ACS), 2003) Department of Chemistry; Department of Chemistry; Department of Chemistry; Department of Chemistry; Department of Chemistry; Yılgör, Emel; Gördeslioğlu, Mehmet; Dizman, Bekir; Yılgör, İskender; Researcher; Undergraduate Student; Undergraduate Student; Faculty Member; College of Sciences; College of Sciences; College of Sciences; College of Sciences; N/A; 40527; 24181; N/AIncorporation of metal salts into polymeric materials leads to improvements in thermal, mechanical and electrical properties of the system. Depending on the structure and the oxidation state of the metal ion, these materials also display interesting optoelectronic properties. Silicone-urea copolymers containing various amounts of CoCl2.6H(2)O were prepared by solution blending. The level of metal incorporation ranged from 10% to 100% on molar basis. Products obtained were characterized by infrared spectroscopy, thermal analyses and stress-strain tests. In order to understand the mechanism of complex formation, quantum mechanical calculations were carried out on model 1,3-dimethylurea/Co(II) systems. Blends of 1,3-dimethylurea and CoCl2.6H(2)O were also prepared and analyzed by infrared spectroscopy.