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The first alkaline-earth azidoaurate(III), Ba[Au(N-3)(4)](2) center dot 4 H2O

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dc.contributor.coauthorProts, Yurii
dc.contributor.coauthorJach, Franziska
dc.contributor.coauthorAfyon, Semih
dc.contributor.coauthorHöhn, Peter
dc.contributor.departmentDepartment of Chemistry
dc.contributor.kuauthorSomer, Mehmet Suat
dc.contributor.kuauthorSubaşı, Yaprak
dc.contributor.kuauthorTekin, Elif Sena
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-10T00:10:55Z
dc.date.issued2023
dc.description.abstractTransparent, dark orange Ba[Au(N-3)(4)](2) center dot 4 H2O was synthesized by reaction of Ba(N-3)(2) and AuCl3 or HAuCl4 in aqueous solution. The novel barium tetraazidoaurate(III) tetrahydrate crystallizes in the monoclinic space group Cc (no. 9) with a=1813.68(17) pm, b=1737.95(11) pm, c=682.04(8) pm and beta=108.849(4)degrees. The predominant structural features of Ba[Au(N-3)(4)](2) center dot 4 H2O are two crystallographically independent discrete anions [Au(N-3)(4)](-) with gold in a tetragonal planar coordination by nitrogen. Vibrational spectra show good agreement with those of other azidoaurates(III). Upon drying, this salt was shown to be a highly explosive material.
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.indexedbyPubMed
dc.description.openaccessYES
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuN/A
dc.description.sponsorshipProjekt DEAL The authors would like to thank Bodo Boehme for helpful discussions and Koc University Surface Science and Technology Center (KUYTAM) for the use of facilities for Raman and IR measurements. Open Access funding enabled and organized by Projekt DEAL.
dc.identifier.doi10.1002/chem.202203501
dc.identifier.eissn1521-3765
dc.identifier.issn0947-6539
dc.identifier.quartileQ2
dc.identifier.scopus2-s2.0-85146473835
dc.identifier.urihttps://doi.org/10.1002/chem.202203501
dc.identifier.urihttps://hdl.handle.net/20.500.14288/17370
dc.identifier.wos914729800001
dc.keywordsAlkaline-earth metals
dc.keywordsAzides
dc.keywordsCrystal structures
dc.keywordsGold
dc.keywordsVibrational spectroscopy
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofChemistry-A European Journal
dc.subjectChemistry
dc.subjectChemistry, physical and theoretical
dc.subjectChemistry, technical
dc.titleThe first alkaline-earth azidoaurate(III), Ba[Au(N-3)(4)](2) center dot 4 H2O
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorSubaşı, Yaprak
local.contributor.kuauthorTekin, Elif Sena
local.contributor.kuauthorSomer, Mehmet Suat
local.publication.orgunit1College of Sciences
local.publication.orgunit2Department of Chemistry
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relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb
relation.isParentOrgUnitOfPublicationaf0395b0-7219-4165-a909-7016fa30932d
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