Publication:
Probing the urea hard domain connectivity in segmented, non-chain extended polyureas using hydrogen-bond screening agents

Simple item page
dc.contributor.coauthorDas, Sudipto
dc.contributor.coauthorWilkes, Garth L.
dc.contributor.departmentDepartment of Chemistry
dc.contributor.facultymemberYes
dc.contributor.kuauthorYılgör, Emel
dc.contributor.kuauthorYılgör, İskender
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-09T23:34:30Z
dc.date.issued2008
dc.description.abstractThe effects of long-range connectivity between urea hard domains on the microphase morphology and mechanical properties of novel, segmented, non-chain extended polyureas based on single isocyanate molecules were analyzed. This was achieved by systematic disruption of the intermolecular bidentate hydrogen bonding between the urea hard segments by the incorporation of a hydrogen bond screener, LiCl. A systematic decrease in the breadth of the service temperature window and. mechanical properties of the polyureas were observed in the presence of LiCl, due to the disruption of the long range connectivity between the hard segments. The above mentioned effects were also found to be dependent on the symmetry of the diisocyanate hard segments.
dc.description.fulltextNo
dc.description.harvestedfromManual
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.openaccessNO
dc.description.peerreviewstatusN/A
dc.description.publisherscopeInternational
dc.description.readpublishN/A
dc.description.sponsoredbyTubitakEuN/A
dc.description.sponsorshipThis project was supported by the U.S. Army Research Laboratory and the U.S. Army Research Office under grant number (DAAD19-02-1-0275) Macromolecular Architecture for Performance (MAP) MURI.
dc.description.studentonlypublicationNo
dc.description.studentpublicationNo
dc.description.versionN/A
dc.identifier.WoSQuartileQ1
dc.identifier.doi10.1016/j.polymer.2007.10.046
dc.identifier.eissn1873-2291
dc.identifier.embargoN/A
dc.identifier.endpage179
dc.identifier.grantnoDAAD19-02-1-0275
dc.identifier.issn0032-3861
dc.identifier.issue1
dc.identifier.scopus2-s2.0-37549020353
dc.identifier.startpage174
dc.identifier.urihttps://doi.org/10.1016/j.polymer.2007.10.046
dc.identifier.urihttps://hdl.handle.net/20.500.14288/12362
dc.identifier.volume49
dc.identifier.wos000253037200002
dc.keywordsHydrogen-bonding
dc.keywordsPolyurea
dc.keywordsMicrophase structure-property relationships
dc.keywordsTetra-amide units
dc.keywordsLithium-chloride
dc.keywordsMorphology development
dc.keywordsPoly(phenylene oxide)
dc.keywordsPhase connectivity
dc.keywordsMolecular-weight
dc.keywordsPolyurethanes
dc.keywordsCopolymers
dc.keywordsSymmetry
dc.language.isoeng
dc.publisherElsevier Sci Ltd
dc.relation.affiliationKoç University
dc.relation.collectionKoç University Institutional Repository
dc.relation.ispartofPolymer
dc.relation.openaccessN/A
dc.rightsN/A
dc.subjectMorphology
dc.subjectPolymerization
dc.subjectHydrogen-bond screening agents
dc.titleProbing the urea hard domain connectivity in segmented, non-chain extended polyureas using hydrogen-bond screening agents
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorYılgör, İskender
local.contributor.kuauthorYılgör, Emel
relation.isOrgUnitOfPublication035d8150-86c9-4107-af16-a6f0a4d538eb
relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb
relation.isParentOrgUnitOfPublicationaf0395b0-7219-4165-a909-7016fa30932d
relation.isParentOrgUnitOfPublication.latestForDiscoveryaf0395b0-7219-4165-a909-7016fa30932d

Files

Collections

Publications without Fulltext