Publication: Synthesis and characterisation of 1,3‐bis(2‐benzimidazyl)‐2‐thiapropane, 1,5‐bis(2‐benzimidazyl)‐3‐thiapentane ligands and their PdCl2 complexes
Program
KU-Authors
KU Authors
Co-Authors
Aghatabay, Naz M
Baykal, A
Advisor
Publication Date
Language
English
Type
Journal Title
Journal ISSN
Volume Title
Abstract
The 1,3-bis(2-benzimidazyl)-2-thiapropane (TP2) and 1,5-bis(2-benzimidazyl)-3-thiapentane (TP3) ligands form 5-coordinate square pyramidal monometallic complexes with PdCl2. In both complexes the ligands act as chelating tridentate, through two of the nitrogen atoms in the imidazole ring and the sulphur atom of the bridging group. The ligands and complexes were characterised by analytical data and by modern spectroscopic methods such as FT-Raman, i.r., H-1 and C-13- n.m.r. spectra.
Description
Source:
Transition Metal Chemistry
Publisher:
Springer
Keywords:
Subject
Chemistry, Chemistry, Inorganic, Nuclear chemistry