Publication:
Highly stable SI-C linked functionalized monolayers on the silicon (100) surface

dc.contributor.coauthorSieval, A.B.
dc.contributor.coauthorNissink, J.W.M.
dc.contributor.coauthorLinford, M.R.
dc.contributor.coauthorVan Der Maas, J.H.
dc.contributor.coauthorDe Jeu, W.H.
dc.contributor.coauthorZuilhof, H.
dc.contributor.coauthorSudhölter, E.J.R
dc.contributor.departmentDepartment of Chemistry
dc.contributor.kuauthorDemirel, Adem Levent
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.date.accessioned2024-11-09T23:02:26Z
dc.date.issued1998
dc.description.abstractMonolayers that are bonded via a covalent Si-C bond are prepared on a silicon(100) surface by reaction of a 1-alkene with the hydrogen-terminated silicon surface. The monolayers have been analyzed by infrared spectroscopy, X-ray reflectivity, and water contact angle measurements and display a remarkably high thermal stability. The reaction also works well for ω-functionalized 1-alkenes, provided that the functional group is properly protected. After formation of the monolayer, the protecting group can be easily removed without noticeable disturbance of the monolayer integrity, and the now reactive sites at the monolayer can be used for further functionalization, as has been shown in the case of ester-protected alcohol and carboxylic acids. Functional groups that are too close to the alkene moiety interfere with monolayer formation and yield disordered monolayers.
dc.description.indexedbyScopus
dc.description.indexedbyWOS
dc.description.issue7
dc.description.openaccessYES
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuN/A
dc.description.volume14
dc.identifier.doi10.1021/la971139z
dc.identifier.issn0743-7463
dc.identifier.quartileQ2
dc.identifier.scopus2-s2.0-0032021791
dc.identifier.urihttps://doi.org/10.1021/la971139z
dc.identifier.urihttps://hdl.handle.net/20.500.14288/8276
dc.keywordsChemical bonds
dc.keywordsContact angle
dc.keywordsElectromagnetic wave reflection
dc.keywordsInfrared spectroscopy
dc.keywordsOlefins
dc.keywordsSilicon carbide
dc.keywordsThermodynamic stability
dc.keywordsHydrogen terminated silicon surface
dc.keywordsMonolayers
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofLangmuir
dc.subjectChemistry
dc.titleHighly stable SI-C linked functionalized monolayers on the silicon (100) surface
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorDemirel, Adem Levent
local.publication.orgunit1College of Sciences
local.publication.orgunit2Department of Chemistry
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relation.isOrgUnitOfPublication.latestForDiscovery035d8150-86c9-4107-af16-a6f0a4d538eb
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