Publication:
A zinc(II) metal organic framework based on flexible o-phenylenediacetate and rigid 4,4′-azobis(pyridine) ligands: synthesis, crystal structure and hydrogen gas adsorption property

dc.contributor.coauthorGunay, Gunes
dc.contributor.coauthorYesilel, Okan Zafer
dc.contributor.coauthorErer, Hakan
dc.contributor.coauthorTabak, Ahmet
dc.contributor.departmentDepartment of Chemical and Biological Engineering
dc.contributor.kuauthorKeskin, Seda
dc.contributor.kuprofileFaculty Member
dc.contributor.yokid40548
dc.date.accessioned2024-11-09T23:25:00Z
dc.date.issued2015
dc.description.abstractA new three-dimensional (3D) metal organic framework, [Zn-2(mu(4)-o-pda)(2)(mu-abpy)](n) (1), has been synthesized by the hydrothermal reaction and characterized by FT-IR spectroscopy, elemental analysis, thermal analysis, X-ray powder diffraction, and single crystal X-ray diffraction techniques (o-H(2)pda = o-phenylenediacetic acid and abpy = 4,4'-azobis(pyridine)). Single crystal X-ray diffraction study reveals that complex 1 exhibits a binodal (3,7)-connected three-dimensional framework (3D) with the point symbol of (3.5(2))(3(2).4(4).5(7).6(7).7). Thermal analysis reveal that complex 1 is stable up to 300 degrees C. In order to investigate the potential of 1 in gas storage applications, we performed experiments and atomically detailed simulations to obtain H-2 adsorption isotherm at a pressure range of 0-1 atm at 77 K.
dc.description.indexedbyWoS
dc.description.indexedbyScopus
dc.description.openaccessNO
dc.description.publisherscopeInternational
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [1649B031402373]
dc.description.sponsorshipScientific Research Fund of Eskisehir Osmangazi University [201519029] This work has been supported by the Scientific and Technological Research Council of Turkey (TUBITAK, No: 1649B031402373) and the Scientific Research Fund of Eskisehir Osmangazi University (Project number: 201519029).
dc.description.volume100
dc.identifier.doi10.1016/j.poly.2015.07.017
dc.identifier.eissn1873-3719
dc.identifier.issn0277-5387
dc.identifier.quartileQ2
dc.identifier.scopus2-s2.0-84938921788
dc.identifier.urihttp://dx.doi.org/10.1016/j.poly.2015.07.017
dc.identifier.urihttps://hdl.handle.net/20.500.14288/11295
dc.identifier.wos365363100014
dc.keywordsO-Phenylenediacetate
dc.keywords4.4 '-Azobis(Pyridine)
dc.keywordsZinc(Ii) Complex
dc.keywordsCoordination polymer
dc.keywordsMetal organic framework coordination polymers
dc.keywordsSimulations
dc.keywordsComplexes
dc.keywordsIsomerism
dc.keywordsCadmium
dc.keywordsCarbons
dc.keywordsFamily
dc.languageEnglish
dc.publisherPergamon-Elsevier Science Ltd
dc.sourcePolyhedron
dc.subjectChemistry
dc.subjectInorganic and nuclear chemistry
dc.subjectCrystallography
dc.titleA zinc(II) metal organic framework based on flexible o-phenylenediacetate and rigid 4,4′-azobis(pyridine) ligands: synthesis, crystal structure and hydrogen gas adsorption property
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.authorid0000-0001-5968-0336
local.contributor.kuauthorKeskin, Seda
local.publication.orgunit1College of Engineering
local.publication.orgunit2Department of Chemical and Biological Engineering
relation.isOrgUnitOfPublicationc747a256-6e0c-4969-b1bf-3b9f2f674289
relation.isOrgUnitOfPublication.latestForDiscoveryc747a256-6e0c-4969-b1bf-3b9f2f674289

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