Publication:
The cluster anion Si-9(4-)

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von Schnering, HG
Kaupp, M
Carrillo-Cabrera, W
Baitinger, M
Schmeding, A
Grin, Y

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Abstract

Solely on the basis of Raman spectra and quantum chemical calculations, the previously unknown cluster anion Si94− (structure shown) was characterized and its structure determined. The anion is formed as a component of solid phases by the thermal decomposition of alkali metal monosilicides.

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Wiley

Keywords

Chemistry, Raman spectroscopy

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Angewandte Chemie-International Edition

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10.1002/(SICI)1521-3773(19980918)37:17<2359

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