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Probing water adsorption characteristics of Pt step-edge decorated CU (211) surface

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dc.contributor.departmentDepartment of Chemistry
dc.contributor.departmentGraduate School of Sciences and Engineering
dc.contributor.departmentKUTEM (Koç University Tüpraş Energy Center)
dc.contributor.kuauthorKaya, Sarp
dc.contributor.kuauthorMohammadpour, Amin
dc.contributor.schoolcollegeinstituteCollege of Sciences
dc.contributor.schoolcollegeinstituteGRADUATE SCHOOL OF SCIENCES AND ENGINEERING
dc.contributor.schoolcollegeinstituteResearch Center
dc.date.accessioned2024-12-29T09:39:51Z
dc.date.issued2024
dc.description.abstractThe surface structure and atomic composition can affect the adsorption characteristics of water on metal surfaces. In this study, we investigated the adsorption of water on Cu(211) stepped surfaces decorated with Pt by a combination of infrared reflection absorption spectroscopy (IRRAS) and temperature -programmed desorption (TPD) studies. We have observed that step sites of Cu can increase the strength of the binding of water molecules to the surface and facilitate water partial dissociation and the formation of OH groups on the surface. Step decoration by Pt can change the water adsorption characteristics and eliminate the water dissociation. Water adsorbs molecularly on the fully Pt -decorated steps of the Cu(211) surface. Molecular water and OH adsorbed on Cu(211), which can make a chain structure, are disrupted with Pt atoms.
dc.description.indexedbyWOS
dc.description.indexedbyScopus
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuTÜBİTAK
dc.description.sponsorshipThis work was supported by The Scientific and Technical Research Council of Turkiye (TUBITAK) (Grant number: 118F137) .
dc.description.volume748
dc.identifier.doi10.1016/j.susc.2024.122537
dc.identifier.eissn1879-2758
dc.identifier.issn0039-6028
dc.identifier.quartileQ3
dc.identifier.scopus2-s2.0-85196783650
dc.identifier.urihttps://doi.org/10.1016/j.susc.2024.122537
dc.identifier.urihttps://hdl.handle.net/20.500.14288/23137
dc.identifier.wos1261616600001
dc.keywordsStepped surfaces
dc.keywordsPt deposition
dc.keywordsCu(211)
dc.keywordsWater adsorption
dc.language.isoeng
dc.publisherElsevier
dc.relation.ispartofSurface Science
dc.subjectChemistry, physical
dc.subjectPhysics, condensed matter
dc.titleProbing water adsorption characteristics of Pt step-edge decorated CU (211) surface
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.kuauthorMohammadpour, Amin
local.contributor.kuauthorKaya, Sarp
local.publication.orgunit1College of Sciences
local.publication.orgunit1GRADUATE SCHOOL OF SCIENCES AND ENGINEERING
local.publication.orgunit1Research Center
local.publication.orgunit2Department of Chemistry
local.publication.orgunit2KUTEM (Koç University Tüpraş Energy Center)
local.publication.orgunit2Graduate School of Sciences and Engineering
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