Publication: Vibrational and thermal studies of [MBr2(p-methylaniline)2] (M: Zn2+, Cd2+ and Hg2+) complexes
Program
KU-Authors
KU Authors
Co-Authors
Golcuk, K
Altun, A
Kumru, M
Advisor
Publication Date
Language
English
Type
Journal Title
Journal ISSN
Volume Title
Abstract
The complexes of MBr2L2 W: Zn(II), Cd(H) and Hg(II); L: p-methylaniline) were prepared and characterized by their elemental analyses, thermal analyses, IR spectra and Raman spectra. The observed IR and Raman bands of the complexes were assigned. Coordination effects on internal modes of p-methylanitine were discussed. FT-IR and FT-Raman spectra show that Zn(II) complex possess a tetrahedral environment around metal ion with C-2v symmetry, whereas Cd(II) and Hg(II) complexes have 5-coordinate polymeric bromide bridged structures around metal ions.
Description
Source:
Vibrational Spectroscopy
Publisher:
Elsevier Science Bv
Keywords:
Subject
Chemistry, Analytical, Chemistry, Physical theoretical, Spectroscopy