Publication:
2d -> 3d polycatenated and 3d -> 3d interpenetrated metal-organic frameworks constructed from thiophene-2,5-dicarboxylate and rigid bis(imidazole) ligands

dc.contributor.coauthorErer, Hakan
dc.contributor.coauthorYesilel, Okan Zafer
dc.contributor.coauthorArici, Mursel
dc.contributor.coauthorBuyukgungor, Orhan
dc.contributor.departmentDepartment of Chemical and Biological Engineering
dc.contributor.kuauthorKeskin, Seda
dc.contributor.kuprofileFaculty Member
dc.contributor.yokid40548
dc.date.accessioned2024-11-09T22:58:31Z
dc.date.issued2014
dc.description.abstractHydrothermal reactions of rigid 1,4-bis(imidazol-1-yl)benzene (dib) and 1,4-bis(imidazol-1-yl)-2, 5-dimethylbenzene (dimb) with deprotonated thiophene-2,5-dicarboxylic acid (H(2)tdc) in the presence of Zn(II) and Cd(II) salts in H2O produced three new metal-organic frameworks, namely, [Zn(mu-tdc)(H2O) (mu-dib)](n) (1), [Cd(mu-tdc)(H2O)(mu-dib)(n) (2), and {[Cd-2(mu(3)-tdc)(2)(mu-dimb)(2)] center dot (H2O)}(n) (3). These MOFs were characterized by FT-IR spectroscopy, elemental, thermal (TG, DTA, DTG and DSC), and single-crystal X-ray diffraction analyses. Isomorphous complexes 1 and 2 reveal polycatenated 2D+2D -> 3D framework based on an undulated (4,4)-sql layer. Complex 3 exhibits a new 4-fold interpenetrating 3D framework with the point symbol of 6(6). Molecular simulations were used to assess the potentials of the complexes for H-2 storage application. Moreover, these coordination polymers exhibit blue fluorescent emission bands in the solid state at room temperature.
dc.description.indexedbyWoS
dc.description.indexedbyScopus
dc.description.issue1
dc.description.openaccessYES
dc.description.publisherscopeInternational
dc.description.sponsoredbyTubitakEuN/A
dc.description.sponsorshipResearch Fund of Eskisehir Osmangazi University [201219C101] This work was supported by the Research Fund of Eskisehir Osmangazi University by project Number: 201219C101.
dc.description.volume210
dc.identifier.doi10.1016/j.jssc.2013.11.036
dc.identifier.eissn1095-726X
dc.identifier.issn0022-4596
dc.identifier.quartileQ2
dc.identifier.scopus2-s2.0-84890480402
dc.identifier.urihttp://dx.doi.org/10.1016/j.jssc.2013.11.036
dc.identifier.urihttps://hdl.handle.net/20.500.14288/7736
dc.identifier.wos330081900040
dc.keywords2D -> 3D Polycatenated
dc.keywords3D -> 3D Interpenetrated
dc.keywordsMetal-organic frameworks
dc.keywordsThiophene-2,5-dicarboxylate complexes
dc.keywordsBis(imidazole) ligands
dc.languageEnglish
dc.publisherElsevier
dc.sourceJournal of Solid State Chemistry
dc.subjectChemistry, inorganic and nuclear
dc.subjectChemistry, physical
dc.title2d -> 3d polycatenated and 3d -> 3d interpenetrated metal-organic frameworks constructed from thiophene-2,5-dicarboxylate and rigid bis(imidazole) ligands
dc.typeJournal Article
dspace.entity.typePublication
local.contributor.authorid0000-0001-5968-0336
local.contributor.kuauthorKeskin, Seda
local.publication.orgunit1College of Engineering
local.publication.orgunit2Department of Chemical and Biological Engineering
relation.isOrgUnitOfPublicationc747a256-6e0c-4969-b1bf-3b9f2f674289
relation.isOrgUnitOfPublication.latestForDiscoveryc747a256-6e0c-4969-b1bf-3b9f2f674289

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