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Publication Metadata only [BMIM] [PF6] incorporation doubles CO2 selectivity of ZIF-8: elucidation of interactions and their consequences on performance(Amer Chemical Soc, 2016) N/A; N/A; N/A; N/A; N/A; Department of Chemical and Biological Engineering; Department of Chemical and Biological Engineering; Kınık, Fatma Pelin; Altıntaş, Çiğdem; Balcı, Volkan; Koyutürk, Burak; Uzun, Alper; Keskin, Seda; Master Student; Researcher; PhD Student; Master Student; Faculty Member; Faculty Member; Department of Chemical and Biological Engineering; Koç University Tüpraş Energy Center (KUTEM) / Koç Üniversitesi Tüpraş Enerji Merkezi (KÜTEM); Graduate School of Sciences and Engineering; Graduate School of Sciences and Engineering; Graduate School of Sciences and Engineering; Graduate School of Sciences and Engineering; College of Engineering; College of Engineering; N/A; N/A; N/A; N/A; 59917; 40548Experiments were combined with atomically detailed simulations and density functional theory (DFT) calculations to understand the effect of incorporation of an ionic liquid (IL), 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]), into a metal organic framework (MOF with a zeolitic imidazolate framework), ZIF-8, on the CO2 separation performance. The interactions between [BMIM] [PF6] and ZIF-8 were examined in deep detail, and their consequences on CO2/CH4, CO2/N-2, and CH4/N-2 separation have been elucidated by using experimental measurements complemented by DFT calculations and atomically detailed simulations. Results suggest that IL-MOF interactions strongly affect the gas affinity of materials at low pressure, whereas available pore volume plays a key role for gas adsorption at high pressures. Direct interactions between IL and MOF lead to at least a doubling of CO2/CH4 and CO2/N-2 selectivities of ZIF-8. These results provide opportunities for rational design and development of IL-incorporated MOFs with exceptional selectivity for target gas separation applications.Publication Metadata only A communication theoretical modeling of axonal propagation in hippocampal pyramidal neurons(IEEE-Inst Electrical Electronics Engineers Inc, 2017) N/A; N/A; Department of Electrical and Electronics Engineering; Ramezani, Hamideh; Akan, Özgür Barış; PhD Student; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; N/A; 6647Understandingthe fundamentals of communication among neurons, known as neuro-spike communication, leads to reach bio-inspired nanoscale communication paradigms. In this paper, we focus on a part of neuro-spike communication, known as axonal transmission, and propose a realistic model for it. The shape of the spike during axonal transmission varies according to previously applied stimulations to the neuron, and these variations affect the amount of information communicated between neurons. Hence, to reach an accurate model for neuro-spike communication, the memory of axon and its effect on the axonal transmission should be considered, which are not studied in the existing literature. In this paper, we extract the important factors on the memory of axon and define memory states based on these factors. We also describe the transition among these states and the properties of axonal transmission in each of them. Finally, we demonstrate that the proposed model can follow changes in the axonal functionality properly by simulating the proposed model and reporting the root mean square error between simulation results and experimental data.Publication Metadata only A communication theoretical modeling of single-layer graphene photodetectors and efficient multireceiver diversity combining(Ieee-Inst Electrical Electronics Engineers Inc, 2012) N/A; Department of Electrical and Electronics Engineering; Gülbahar, Burhan; Akan, Özgür Barış; PhD Student; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; 234525; 6647Graphene with groundbreaking properties has tremendous impact on physical sciences as 2-D atomic layer carbon sheet. Its unique electronic and photonic properties lead to applications such as transistors, graphene photodetectors (GPDs), and electronic circuit components. Metal-graphene-metal (MGM) GPDs with single-or multilayer graphene sheets are promising for future nanoscale optical communication architectures because of wide range absorption from far infrared to visible spectrum, fast carrier velocity, and advanced production techniques due to planar geometry. In this paper, signal-to-noise ratio (SNR), bit-error rate (BER), and data rate performances of nanoscale single-layer symmetric MGM photodetectors are analyzed for intensity modulation and direct detection (IM/DD) modulation. Shot and thermal noise limited (NL) performances are analyzed emphasizing graphene layer width dependence and domination of thermal NL characteristics for practical power levels. Tens of Gbit/s data rates are shown to be achievable with very low BERs for single-receiver (SR) GPDs. Furthermore, multireceiver (MR) GPDs and parallel line-scan (PLS) network topology are defined improving the efficiency of symmetric GPDs. SNR performance of SR PLS channels are both improved and homogenized with MR devices having the same total graphene area by optimizing their positions with maxmin solutions and using maximal ratio and equal gain diversity combining techniques.Publication Metadata only A communication theoretical modeling of single-walled carbon nanotube optical nanoreceivers and broadcast power allocation(Ieee-Inst Electrical Electronics Engineers Inc, 2012) N/A; Department of Electrical and Electronics Engineering; Gülbahar, Burhan; Akan, Özgür Barış; PhD Student; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; 234525; 6647Carbon nanotube (CNT) with its ground-breaking properties is a promising candidate for future nanoscale communication networks. CNTs can be used as on-chip optical antenna for wireless interconnects. Carbon nanotube field-effect transistors (CNTFETs) show significant performance as photodetectors due to wide spectral region and tunable bandgap. In this paper, CNTFETs composed of semiconducting single-walled carbon nanotube (SWNT) and metal contacts (M-SWNT-M) are used as photodiode receivers in nanoscale optical communication by theoretically modeling diameter-dependent characteristics for shot-, dark-, and thermal-noise-limited cases. Bit error rate (BER), cutoff bit rate, and signal-to-noise ratio performance are analyzed for intensity modulation and direct detection modulation. The multireceiver CNT nanoscale network topology is presented for information broadcast and the minimum SNR is maximized solving NP-hard max-min power allocation problem with semidefinite programming relaxation and branch and bound framework. The significant performance improvement is observed compared with uniform power allocation. Derived model is compared with existing experiments and hundreds of Mb/s data rate is achievable with very low BERs. Furthermore, optimization gain is highest for thermal-noise-limited case while the shot-noise-limited case gives the highest data rate.Publication Metadata only A comprehensive evaluation of parameters governing the cyclic stability of ultrafine-grained FCC alloys(Elsevier Science Sa, 2011) Niendorf, T.; Maier, H. J.; Department of Mechanical Engineering; Canadinç, Demircan; Faculty Member; Department of Mechanical Engineering; College of Engineering; 23433The current paper presents results of a thorough experimental program undertaken to shed light onto the mechanisms dictating the cyclic stability in ultrafine-grained (UFG) alloys with a face-centered cubic structure. Cyclic deformation responses of several copper- and aluminum-based UFG alloys were investigated and the corresponding microstructural evolutions were analyzed with various microscopy techniques. The important finding is that a larger volume fraction of high-angle grain boundaries and solid solution hardening significantly improve the fatigue performance of these alloys at elevated temperatures and high strain rates, and under large applied strain amplitudes.Publication Metadata only A computational study of drop formation in an axisymmetric flow-focusing device(Amer Soc Mechanical Engineers, 2006) Department of Mechanical Engineering; Department of Mechanical Engineering; Filiz, İsmail; Muradoğlu, Metin; N/A; Faculty Member; Department of Mechanical Engineering; College of Engineering; College of Engineering; N/A; 46561We investigate the formation and dynamics of drops computationally in an axisymetric geometry using a Front-Tracking/Finite-Difference (FT/FD) method. The effects of viscosity ratio between inner and outer liquids on the drop creation process and drop size distribution are examined. It is found that the viscosity ratio critically influences the drop formation process and the final drop distribution. We found that, for small viscosity ratios, i.e., 0.1 < lambda < 0.5 drop size is about the size of the orifice and drop distribution is highly monodisperse. When viscosity ratio is increased, i.e., 0.5 < lambda < I a smaller drop is created just after the main drop. For even higher viscosity ratios, the drop distribution is usually monodisperse but a satellite drop is created in some cases. The effect of the flow rates in the inner jet and the co flowing annulus are also studied. It is found that the drop size gets smaller as Q(in) / Q(out) is reduced while keeping the outer flow rate constant.Publication Metadata only A deep etching mechanism for trench-bridging silicon nanowires(Iop Publishing Ltd, 2016) Wollschlaeger, Nicole; Österle, Werner; Leblebici, Yusuf; N/A; Department of Mechanical Engineering; Taşdemir, Zuhal; Alaca, Burhanettin Erdem; PhD Student; Faculty Member; Department of Mechanical Engineering; Koç University Surface Science and Technology Center (KUYTAM) / Koç Üniversitesi Yüzey Teknolojileri Araştırmaları Merkezi (KUYTAM); Graduate School of Sciences and Engineering; College of Engineering; N/A; 115108Introducing a single silicon nanowire with a known orientation and dimensions to a specific layout location constitutes a major challenge. The challenge becomes even more formidable, if one chooses to realize the task in a monolithic fashion with an extreme topography, a characteristic of microsystems. The need for such a monolithic integration is fueled by the recent surge in the use of silicon nanowires as functional building blocks in various electromechanical and optoelectronic applications. This challenge is addressed in this work by introducing a topdown, silicon-on-insulator technology. The technology provides a pathway for obtaining wellcontrolled silicon nanowires along with the surrounding microscale features up to a three-orderof-magnitude scale difference. A two-step etching process is developed, where the first shallow etch defines a nanoscale protrusion on the wafer surface. After applying a conformal protection on the protrusion, a deep etch step is carried out forming the surrounding microscale features. A minimum nanowire cross-section of 35 nm by 168 nm is demonstrated in the presence of an etch depth of 10 mu m. Nanowire cross-sectional features are characterized via transmission electron microscopy and linked to specific process steps. The technology allows control on all dimensional aspects along with the exact location and orientation of the silicon nanowire. The adoption of the technology in the fabrication of micro and nanosystems can potentially lead to a significant reduction in process complexity by facilitating direct access to the nanowire during surface processes such as contact formation and doping.Publication Metadata only A deformation-based approach to tuning of magnetic micromechanical resonators(2018) Yalçınkaya, Arda D.; Department of Mechanical Engineering; N/A; Department of Mechanical Engineering; Biçer, Mahmut; Esfahani, Mohammad Nasr; Alaca, Burhanettin Erdem; Researcher; PhD Student; Faculty Member; Department of Mechanical Engineering; Koç University Surface Science and Technology Center (KUYTAM) / Koç Üniversitesi Yüzey Teknolojileri Araştırmaları Merkezi (KUYTAM); College of Engineering; Graduate School of Sciences and Engineering; College of Engineering; N/A; N/A; 115108Resonance frequency tuning in magnetic micromechanical resonators remains a primary field of study for frequency reference applications. The use of magnetic micromechanical resonators for innovative timing, oscillator and sensing applications necessitates a platform for the precise control of the resonance frequency. The present work addresses a deformation based technique for tuning the resonance frequency of nickel micromechanical resonators. Frequency response is measured through magnetic actuation and optical readout. The tuning approach is based on a combination of flexural deformation and uniaxial strain. The bending deformation is achieved by using a DC current through the microbeam. This magnetomotive mechanism reduces the resonance frequency by about 13% for a maximum DC current of 80 mA. A substrate bending method is used for applying uniaxial strain to increase the resonance frequency by about 8%. A bidirectional frequency modulation is thus demonstrated by utilizing both deformation techniques. The interpretation of results is carried out by finite element analysis and electromechanical analogy in an equivalent circuit. Using deformation techniques, this study provides a rigorous approach to control the resonance frequency of magnetic micromechanical resonators.Publication Metadata only A fast algorithm for analysis of molecular communication in artificial synapse(IEEE-Inst Electrical Electronics Engineers Inc, 2017) N/A; Department of Electrical and Electronics Engineering; Bilgin, Bilgesu Arif; Akan, Özgür Barış; PhD Student; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; N/A; 6647In this paper, we analyze molecular communications (MCs) in a proposed artificial synapse (AS), whose main difference from biological synapses (BSs) is that it is closed, i.e., transmitter molecules cannot diffuse out from AS. Such a setup has both advantages and disadvantages. Besides higher structural stability, being closed, AS never runs out of transmitters. Thus, MC in AS is disconnected from outer environment, which is very desirable for possible intra-body applications. On the other hand, clearance of transmitters from AS has to be achieved by transporter molecules on the presynaptic membrane of AS. Except from these differences, rest of AS content is taken to be similar to that of a glutamatergic BS. Furthermore, in place of commonly used Monte Carlo-based random walk experiments, we derive a deterministic algorithm that attacks for expected values of desired parameters such as evolution of receptor states. To assess validity of our algorithm, we compare its results with average results of an ensemble of Monte Carlo experiments, which shows near exact match. Moreover, our approach requires significantly less amount of computation compared with Monte Carlo approach, making it useful for parameter space exploration necessary for optimization in design of possible MC devices, including but not limited to AS. Results of our algorithm are presented in case of single quantal release only, and they support that MC in closed AS with elevated uptake has similar properties to that in BS. In particular, similar to glutamatergic BSs, the quantal size and the density of receptors are found to be main sources of synaptic plasticity. On the other hand, the proposed model of AS is found to have slower decaying transients of receptor states than BSs, especially desensitized ones, which is due to prolonged clearance of transmitters from AS.Publication Metadata only A Fourier transform spectrometer using resonant vertical comb actuators(Institute of Physics (IOP) Publishing, 2006) Wolter, Alexander; N/A; Department of Electrical and Electronics Engineering; Ataman, Çağlar; Ürey, Hakan; PhD Student; Faculty Member; Department of Electrical and Electronics Engineering; Graduate School of Sciences and Engineering; College of Engineering; N/A; 8579The design, fabrication and characterization of a novel out-of-plane vertical comb-drive actuator based lamellar grating interferometer (LGI) is reported. The interferometer utilizes resonant mode vertical comb actuators, where comb fingers are simultaneously used for actuation and as a movable diffraction grating, making the device very compact. The Fourier transform of the zeroth order intensity pattern as a function of the optical path difference gives the spectrum of light. The main advantages offered by the proposed device are a long travel range (i.e. good spectral resolution), a large clear aperture (i.e. high light efficiency), and a very simple, robust and compact spectrometer structure. Peak-to-peak 106 mu m out-of-plane deflection is observed in ambient pressure and at 28 V, corresponding to a theoretical spectral resolution of about 0.4 nm in the visible band and 3.6 nm at 1.5 mu m. A simple CMOS compatible process based on bulk micromachining of a silicon-on-insulator wafer is used for the device fabrication.